Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Chantall Fedorchuk"'
Publikováno v:
Journal of Organometallic Chemistry. 692:2705-2715
The combined use of theoretical and mathematical methods in the analysis of electron paramagnetic resonance data has greatly increased the ability to interpret even the most complex spectra reported for doublet state inorganic main group radicals. Th
Publikováno v:
Coordination Chemistry Reviews. 251:897-924
The boraamidinate ligand, [RB(NR′) 2 ] 2− , is isoelectronic with the corresponding and extensively studied amidinate ligand, [RC(NR′) 2 ] − . This review provides the first comprehensive account of the coordination chemistry of the boraamidi
Autor:
Tristram Chivers, Gabriele Schatte, Heikki M. Tuononen, Dana J. Eisler, René T. Boeré, Chantall Fedorchuk
Publikováno v:
Inorganic Chemistry. 45:2119-2131
The first magnesium and zinc boraamidinate (bam) complexes have been synthesized via metathetical reactions between dilithio bams and Grignard reagents or MCl2 (M = Mg, Zn). The following new classes of bam complexes have been structurally characteri
Publikováno v:
Organometallics. 24:1919-1928
The preparation of a new family of acyclic DippN(H)P(Ph)NRCR‘NR systems (2a−c) has been achieved by the reaction of the mono(amino)chlorophosphine PhP(Cl)N(H)Dipp (1; Dipp = 2,6-(iPr)2C6H3) with 1 equiv of Li[CR‘(NR)2] (2a, R = tBu, R‘ = nBu;
Publikováno v:
Inorganic Chemistry. 43:2643-2653
The dilithiated boraamidinate complexes [Li(2)[PhB(NDipp)(2)](THF)(3)] (7a) (Dipp = 2,6-diisopropylphenyl) and [Li(2)[PhB(NDipp)(N(t)Bu)](OEt(2))(2)] (7b), prepared by reaction of PhB[N(H)Dipp][N(H)R'] (6a, R' = Dipp; 6b, R' = (t)Bu) with 2 equiv of
Publikováno v:
Inorganic Chemistry. 42:2084-2093
The reactions of [Li(2)[PhB(N(t)Bu)(2)]](2) with GaCl(3) in various stoichiometries yield [Li(thf)(4)][PhB(mu-N(t)Bu)(2)GaCl(2) x GaCl(3)] (1), [PhB(mu-N(t)Bu)(2)GaCl](2) (2), and [mu-Li(OEt(2))[PhB(N(t)Bu)(2)]Ga] (3a), a series of complexes in which
Publikováno v:
Canadian Journal of Chemistry. 80:821-831
The dilithiated boraamidinate complexes {Li2[RB(N-t-Bu)2]}2 (1a, R = Ph; 1b, R = t-Bu), prepared by the reaction of B[N(H)-t-Bu]3 with three equivalents of LiR, are shown by X-ray crystallography to have dimeric structures consisting of a distorted L
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 58:o422-o425
The crystal structure of the title compound is composed of diastereomers of 4-(2-hydroxyphenyl)-2-phenyl-2,3,4,5-tetrahydro-1,5-benzothiazepine, C21H19NOS, that are cocrystallized. The asymmetric unit contains two molecules. One S and two C
Publikováno v:
Inorganic Chemistry. 40:1936-1942
The metathetical reactions of the lithium derivative of the monoanion [((t)BuN)(S)P(mu-N(t)Bu)(2)P(S)(NH(t)Bu)](-) (L) with CuCl/PPh(3), NiCl(2)(PEt(3))(2), PdCl(2)L'(2) (L' = PhCN, PPh(3)), and PtCl(2)(PEt(3))(2) produced the complexes (PPh(3))CuL (
Publikováno v:
ChemInform. 33