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pro vyhledávání: '"Chakrapani P. Patnaik"'
Publikováno v:
Bulletin of the Chemical Society of Japan. 60:3391-3395
The kinetics of oxidation of acetylacetone by peroxomonophosphoric acid and hydrogen peroxide have been investigated in the pH range 8–13.7. The oxidations by peroxomonophosphoric acid at 308 K and I=0.6 mol dm−3 follow the rate expressions,(i)
Autor:
Sabita Kumari Mahapatra, Akhil Krishna Panigrahi, Sabita Kumari Sahu, Chakrapani P. Patnaik, Radhasyam Panda
Publikováno v:
Bulletin of the Chemical Society of Japan. 61:1363-1367
The kinetics of Baeyer-Villiger oxidation of biacetyl and benzil by peroxomonophosphoric acid and peroxomonosulfuric acid have been studied in different pH ranges at 308 K. The reactions are second order; first order each in peroxy acid and in diketo