Zobrazeno 1 - 10
of 40
pro vyhledávání: '"Chakicherla, Gayathri"'
Autor:
Roberto R. Gil, Matthew Y. Sfeir, Chenjie Zeng, Meng Zhou, Rongchao Jin, Chakicherla Gayathri
Publikováno v:
Chinese Journal of Chemical Physics. 31:555-562
Gold(Ⅰ) thiolate compounds (i.e. AuⅠ-SR) are important precursors for the synthesis of atomically precise Aun(SR)m nanoclusters. However, the nature of the AuⅠ-SR precursor remains elusive. Here, we report that the Au10(TBBT)10 complex is a uni
Autor:
Gordon S. Rule, Roberto R. Gil, Kirti Bhatt, Wei-Che Hsieh, Charles A. Thornton, Arnab Mukherjee, Mengshen'David' Chen, Ashif Y. Shaikh, Shivaji A. Thadke, Chakicherla Gayathri, Danith H. Ly, V. M. Hridya, J. Dinithi R. Perera
Publikováno v:
Biochemistry. 57:2094-2108
We report the development of a new class of nucleic acid ligands that is comprised of Janus bases and the MPγPNA backbone and is capable of binding rCAG repeats in a sequence-specific and selective manner via, inference, bivalent H-bonding interacti
Autor:
Joshua C. Worch, Chakicherla Gayathri, Kevin J. T. Noonan, Roberto R. Gil, Yunyan Qiu, Andria Fortney
Publikováno v:
Macromolecules. 49:4757-4762
Controlled synthesis of conjugated polymers with functional side chains is of great importance, affording well-defined optoelectronic materials possessing enhanced stability and tunability as compared to their alkyl-substituted counterparts. Herein,
Autor:
Chakicherla Gayathri, Terrence J. Collins, Liang L. Tang, Rakesh Kanda, Matthew A. DeNardo, Roberto R. Gil
Publikováno v:
Environmental Science & Technology. 50:5261-5268
The extremely persistent molluscicide, metaldehyde, widely used on farms and gardens, is often detected in drinking water sources of various countries at concentrations of regulatory concern. Metaldehyde contamination restricts treatment options. Con
Autor:
Erich Hellemann, Joshua C. Worch, Chakicherla Gayathri, Kevin J. T. Noonan, Tomislav Pintauer, Roberto R. Gil, Gabrielle Pros
Publikováno v:
Organometallics. 34:5366-5373
The synthesis and functionalization of the parent 1,3-benzothiaphosphole is reported. The phosphole could not be isolated, but the compound could be manipulated in solution to produce several new phosphorus compounds. Metalation of the 2-position usi
Autor:
Hongzhu Xing, Chakicherla Gayathri, Chong Liu, Anindita Das, Nathaniel L. Rosi, Rongchao Jin, Renxi Jin, Yan Xing, Shuo Zhao, Roberto R. Gil
Publikováno v:
ACS Nano. 9:8530-8536
The [Au37(PPh3)10(SR)10X2](+) nanocluster (where SR = thiolate and X = Cl/Br) was theoretically predicted in 2007, but since then, there has been no experimental success in the synthesis and structure determination. Herein, we report a kinetically co
Autor:
Shannon R. Woodruff, Eduardo Troche-Pesqueira, Chakicherla Gayathri, Jonathan D. Snider, Roberto R. Gil, Nicolay V. Tsarevsky
Publikováno v:
Magnetic Resonance in Chemistry. 50:S86-S91
A new strategy to assign diastereotopic protons was developed on the basis of residual dipolar couplings (RDCs) collected in compressed poly(methyl methacrylate) (PMMA) gels. A combination of 2D J-scaled BIRD HSQC and J-scaled BIRD HMQC/HSQC NMR expe
Autor:
Matthew A. DeNardo, Rakesh Kanda, Liang L. Tang, Mills, CJ Schuler, Chakicherla Gayathri, Roberto R. Gil, Terrence J. Collins
This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Journal of the American Chemical Society, copyright © American Chemical Society after peer review. To access the final edited and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8c4e9d0ad4946a294778aa78bc780f05
http://bura.brunel.ac.uk/handle/2438/13713
http://bura.brunel.ac.uk/handle/2438/13713
Publikováno v:
ACS Nano. 5:8935-8942
We report the analysis of chirality in atomically precise gold nanoclusters by nuclear magnetic resonance (NMR) spectroscopic probing of the surface ligands. The Au(38)(SR)(24) and Au(25)(SR)(18) (where, R = CH(2)CH(2)Ph) are used as representative m
Publikováno v:
Journal of Catalysis. 271:155-160
Atomically monodisperse Au25(SR)18 (where R CH2CH2Ph) nanoparticles are explored as a stereoselective catalyst for hydrogenation of cyclic ketone to one specific isomer of cyclic alcohol product. A complete (∼100%) stereoselectivity is obtained. Th