Zobrazeno 1 - 10
of 27
pro vyhledávání: '"Chad T, Palumbo"'
Autor:
Chad T. Palumbo, Nina X. Gu, Alissa C. Bleem, Kevin P. Sullivan, Rui Katahira, Lisa M. Stanley, Jacob K. Kenny, Morgan A. Ingraham, Kelsey J. Ramirez, Stefan J. Haugen, Caroline R. Amendola, Shannon S. Stahl, Gregg T. Beckham
Publikováno v:
Nature Communications, Vol 15, Iss 1, Pp 1-12 (2024)
Abstract Efforts to produce aromatic monomers through catalytic lignin depolymerization have historically focused on aryl–ether bond cleavage. A large fraction of aromatic monomers in lignin, however, are linked by various carbon–carbon (C–C) b
Externí odkaz:
https://doaj.org/article/4af11bcfb84a4cdd8637b29f91da4cef
Autor:
Nina X. Gu, Chad T. Palumbo, Alissa C. Bleem, Kevin P. Sullivan, Stefan J. Haugen, Sean P. Woodworth, Kelsey J. Ramirez, Jacob K. Kenny, Lisa D. Stanley, Rui Katahira, Shannon S. Stahl, Gregg T. Beckham
Publikováno v:
ACS Central Science, Vol 9, Iss 12, Pp 2277-2285 (2023)
Externí odkaz:
https://doaj.org/article/c8afedc849cb4cc9af67fc9a91f79ecc
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 76, Iss 9, Pp 1447-1453 (2020)
Studies of the coordination chemistry between the diphenylamide ligand, NPh2, and the smaller rare-earth LnIII ions, Ln = Y, Dy, and Er, led to the structural characterization by single-crystal X-ray diffraction crystallography of both solvated and u
Externí odkaz:
https://doaj.org/article/a449fec5adf94de39a6e9f2df6bcd98e
Autor:
Yu Rao, Chad T. Palumbo, Amrit Venkatesh, Megan Keener, Gabriele Stevanato, Anne-Sophie Chauvin, Georges Menzildjian, Sergei Kuzin, Maxim Yulikov, Gunnar Jeschke, Anne Lesage, Marinella Mazzanti, Lyndon Emsley
Publikováno v:
The Journal of Physical Chemistry C, 126 (27)
Nuclear magnetic resonance suffers from an intrinsically low sensitivity, which can be overcome by dynamic nuclear polarization (DNP). Gd(III) complexes are attractive exogenous polarizing agents for magic angle spinning (MAS) DNP due to their high c
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 76, Iss 9, Pp 1447-1453 (2020)
Studies of the coordination chemistry between the diphenylamide ligand, NPh2, and the smaller rare-earth Ln III ions, Ln = Y, Dy, and Er, led to the structural characterization by single-crystal X-ray diffraction crystallography of both solvated and
Autor:
Farzaneh Fadaei-Tirani, Laurent Maron, Aurélien R. Willauer, Marinella Mazzanti, Ivica Zivkovic, Chad T. Palumbo, Iskander Douair
Publikováno v:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (12), pp.5538-5542. ⟨10.1021/jacs.0c01204⟩
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (12), pp.5538-5542. ⟨10.1021/jacs.0c01204⟩
Out of the 14 lanthanide (Ln) ions, molecular complexes of Ln(IV) were known only for cerium and more recently terbium. Here we demonstrate that the +IV oxidation state is also accessible for the large praseodymium (Pr) cation. The oxidation of the t
Publikováno v:
Journal of the American Chemical Society. 142:3149-3157
Synthetic studies of bimetallic uranium nitride complexes with the N(SiMe3)2 ligand have generated a new nitride complex of U(III), which is highly reactive toward C-H bonds and H2. Treatment of the previously reported U(IV)/U(IV) nitride complex [Na
Autor:
Laurent Maron, Marinella Mazzanti, Iskander Douair, Dieuwertje K. Modder, Chad T. Palumbo, Rosario Scopelliti
Publikováno v:
Chemical Science
Chemical Science, 2021, 12 (17), pp.6153-6158. ⟨10.1039/d1sc00668a⟩
Chemical Science, 2021, 12 (17), pp.6153-6158. ⟨10.1039/d1sc00668a⟩
The redox chemistry of uranium is dominated by single electron transfer reactions while single metal four-electron transfers remain unknown in f-element chemistry. Here we show that the oxo bridged diuranium(iii) complex [K(2.2.2-cryptand)]2[{((Me3Si
Autor:
Laurent Maron, Iskander Douair, Marinella Mazzanti, Farzaneh Fadaei-Tirani, Chad T. Palumbo, Dieuwertje K. Modder
Publikováno v:
Angewandte Chemie-International Edition
Angewandte Chemie-International Edition, 2021, 60 (7), pp.3737-3744. ⟨10.1002/anie.202013473⟩
Angewandte Chemie-International Edition, 2021, 60 (7), pp.3737-3744. ⟨10.1002/anie.202013473⟩
Oxide is an attractive linker for building polymetallic complexes that provide molecular models for metal oxide activity, but studies of these systems are limited to metals in high oxidation states. Herein, we synthesized and characterized the molecu
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications
Crystallographic characterization of complexes of the smaller rare-earth elements Y, Dy, and Er with the NPh2 ligand reveals monometallic, bimetallic, and tetrametallic structures.
Studies of the coordination chemistry between the diphenyl
Studies of the coordination chemistry between the diphenyl