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Publikováno v:
Chemistry, Vol 5, Iss 4, Pp 2682-2699 (2023)
The iron-promoted 1,5-substitution reaction of endocyclic oxiranes with MeMgBr yields exocyclic 2,4,5-trienols with high diastereomeric ratios of up to 100:0. However, for the method’s success, the oxirane ring must have a trans-configuration. The
Externí odkaz:
https://doaj.org/article/c8f42060be4240d48bbbf183827ec46e