Zobrazeno 1 - 10
of 31
pro vyhledávání: '"Cecil L. Frye"'
Publikováno v:
Water, Air, & Soil Pollution. 87:231-243
Our previous publications showed that silicone (polydimethylsiloxane, or PDMS) polymers degrade to monomeric silanols and eventually to C02 in laboratory soil incubations. In this study, 200 cs14C-PDMS was added to soil microcosms (Tuscola sandy loam
Publikováno v:
Science of The Total Environment. 162:193-207
The potential ecological effects of polydimethylsiloxane (PDMS)-augmented sewage sludge resulting from use of the sludge as an agricultural amendment were evaluated in a preliminary pot test and a definitive test in intact, agricultural soil-core mic
Publikováno v:
Environmental Toxicology and Chemistry. 13:1753-1759
Silicone (polydimethylsiloxane, or PDMS) fluids are widely used in industrial and consumer products and may find their way into municipal sludges that are eventually applied to the land. Earlier studies showed that PDMS degrades in soil to low-molecu
Publikováno v:
Environmental Toxicology and Chemistry. 13:1061-1064
Silicone polymers (polydimethylsiloxanes, or PDMS) are used in numerous personal care and household products, eventually enter wastewater treatment plants, and are later applied to the land as a component of sludge. The fate of silicones in soil is l
Autor:
Cecil L. Frye, H.K. Chu
Publikováno v:
Journal of Organometallic Chemistry. 446:183-189
An eight-membered cyclic compound, 2,2,3,4,4,6,6,7,8,8-decamethyl-1,5-dioxa-2,4-disilacyclooctane (VIII), along with the expected five-membered 2,2,5,5-tetramethyl-1-oxa-2-silacyclopentane (V) were found to be the major products when vinyldimethylcar
Autor:
Cecil L. Frye, H. K. Chu
Publikováno v:
ChemInform. 24
Publikováno v:
Environmental Toxicology and Chemistry. 15:1263-1265
The aqueous solubility of several low mlecular weight linear, cyclic, and branched permethylsiloxanes was determined at room temperature. A method for preparing molecularly dispersed, colloid-free saturated aqueous solutions is described. Solubilitie
Autor:
Cecil L. Frye
Publikováno v:
Science of The Total Environment. 73:17-22
In order to assess reliably and safely the potential threats posed by the environmental presence of any class of materials, one must carefully consider a number of key parameters. In addition to chemical reactivity, one must consider a material's phy
Publikováno v:
Environmental Toxicology and Chemistry. 2:307-313
A novel method has been developed for the qualitative and quantitative characterization of (a) waterborne organosilicon substances, which are present as low-molecular-weight silanols (such as silicone hydrolysis products), and (b) higher-molecular-we
Publikováno v:
Environmental Toxicology and Chemistry. 3:215-222
Dimethylsilanediol and other water-soluble dimethysiloxanols undergo aqueous photolytic oxidative demethylation with tropospheric ultraviolet radiation in the presence of suitable chromophores, such as nitrogen oxides, to give silicic acid and carbon