Structure and Dynamics of the Excited States of 1,3-Diarylisobenzofurans: An Experimental and Theoretical Study

Autor: Svetlana Tsekhanovich, Jacques Einhorn, Frédérique Loiseau, Jérôme Jacq, Jérôme Chauvin, Cathy Einhorn, Damien Jouvenot, Bernard Bessieres, Maylis Orio

Publikováno v: Photochemistry and Photobiology
Photochemistry and Photobiology, Wiley, 2012, 88, pp.633-638. ⟨10.1111/j.1751-1097.2012.01090.x⟩
Photochemistry and Photobiology, 2012, 88, pp.633-638. ⟨10.1111/j.1751-1097.2012.01090.x⟩

The emission properties of a series of substituted 1,3-diarylisobenzofurans have been studied. Most compounds exhibit very intense emission in the nanosecond timescale at room temperature as well as at 77 K. The room temperature emission is attribute

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::89bf97ea634710dfb92e0a45b1b177c6
https://doi.org/10.1111/j.1751-1097.2012.01090.x

Efficient chromatographic resolution of a configurationally fragile atropisomeric diphenol via its N-(α)-Boc-tryptophan diesters

Autor: Cathy Einhorn, Jacques Einhorn, Christian Philouze, Bhavesh M. Panchal, Malek Nechab

Publikováno v: Tetrahedron: Asymmetry. 16:1681-1684

Racemic 4,5-bis-(2-hydroxy-phenyl)-benzo[f]isoindole-1,3-dione 2, an atropisomeric diphenol prone to thermal isomerisation, has been efficiently resolved by conversion into its N-(α)-Boc-tryptophan diesters. Easy chromatographic separation of the di

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d79e4169a8318b86f55fdaa608960be3
https://doi.org/10.1016/j.tetasy.2005.03.011

Hydrogen abstraction from ethylbenzene by imide-N-oxyl radicals with and without O2: a DFT theoretical study

Autor: Jacques Einhorn, Carlo Adamo, Cathy Einhorn, Anne Milet, Roger Arnaud

Publikováno v: Journal of the Chemical Society, Perkin Transactions 2. :1967-1972

In this paper, we report a theoretical study of the hydrogen abstraction reactions from ethylbenzene by a series of imide-N-oxyl radicals. Geometry optimizations and vibrational frequencies were performed using density functional theory at the B3LYP/

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3410137238b5afe9191e9ea97ab93e7b
https://doi.org/10.1039/b205485j

Synthesis of a new,C2Symmetric α,α - Bis-(Carboxymethyl) Substituted Nitroxide

Autor: Jean-Louis Pierre, Jacques Einhorn, Cathy Einhorn, Fabien Ratajczak

Publikováno v: Synthetic Communications. 30:1837-1848

The novel, diastereomeric meso- (cis) and (±)- (trans) nitroxides 2,5-dicarboxymethyl-2,5-dimethylpyrrolidine-1-oxyl have been synthesized via a dienolate based strategy. Both optically pure enantiomers of the C 2 symmetric trans diastereomer have b

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::99ec1b5001a38325d9626a5eed6f147b
https://doi.org/10.1080/00397910008087229

Electrocatalytic oxidation of alcohols using substituted N-hydroxyphthalimides as catalysts

Autor: Jean-Louis Pierre, Jacques Einhorn, Celine Marcadal, Karine Gorgy, Jean-Claude Leprêtre, Cathy Einhorn, Eric Saint-Aman

Publikováno v: Electrochimica Acta. 44:385-393

The electrocatalytic oxidation of several alcohols was performed using a new series of substituted N-hydroxyphthalimides as catalysts. The substitution in the N-hydroxyphthalimide structure by electron withdrawing or donor substituents has a benefici

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3f62fe54c4f95a40e51bc561d2921b6e
https://doi.org/10.1016/s0013-4686(97)10189-x