Výsledky vyhledávání - "Cathryn E. Hickey"

Factors influencing the oxidative addition of iodomethane to [Rh(CO)2I2]−, the key step in methanol and methyl acetate carbonylation

Autor: Cathryn E. Hickey, Peter M. Maitlis, Anthony Fulford

Publikováno v: Journal of Organometallic Chemistry. 398:311-323

The oxidative addition of MeI to A + [Rh(CO) 2 I 2 ] − [A = n-Bu 4 N, Ph 4 P, and Ph 4 As], the rate determining step in the Rh and I − catalysed conversion of methanol into acetic acid and of methyl acetate into acetic anhydride, is second order

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4723953df451e85a4dcb461a878f4518
https://doi.org/10.1016/0022-328x(90)85517-3

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Oxidative addition of methyl lodide to dicarbonylrhodium(I) complexes

Autor: Peter M. Maitlis, Cathryn E. Hickey

Publikováno v: Journal of the Chemical Society, Chemical Communications. :1609

Oxidative addition of Mel to [Rh(CO)2l2]– in aprotic solvents, the ‘rate-determining’ step in the carbonylation of methyl acetate and methyl halides(to acetic anhydride and acyl halides, respectively), is substantially promoted by iodide and ba

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7b44332bb6563e7c69122545043ba8c6
https://doi.org/10.1039/c39840001609

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