Zobrazeno 1 - 10
of 31
pro vyhledávání: '"Catherine Vermeil"'
Autor:
Lucette Hellner, Catherine Vermeil
Publikováno v:
Journal of Molecular Spectroscopy. 60:71-92
Benzene isolated in argon or nitrogen matrix at about 5 K has been irradiated with photons of 6 eV (206.2 nm), 8.4 eV (147 nm), and 10 eV (123.6 nm) energy. In every case phosphorescence a 3 B 1u → X 1 A 1g and fluorescence A 1 B 2u → X 1 A 1g ha
Publikováno v:
Journal of Physics E: Scientific Instruments. 9:879-884
An apparatus for the study of emission spectra at low temperatures of excited species produced by photolysis and trapped in a rigid matrix is described. Experimental techniques for obtaining and controlling low temperatures, the preparation and condi
Publikováno v:
The Journal of Chemical Physics. 70:5726-5730
The photolysis of N2O in an argon matrix at 7 °K by 8.4 eV energy photons leads to the emission of the Vegard–Kaplan system of N2 (A 3Σ+→X 1Σ+g) and to the atomic emissions O(1S) →O(1D) and N(2D) →N(4S). The thermoluminescence which accomp
Publikováno v:
Chemical Physics Letters. 83:474-479
When direct or sensitized photolysis of gaseous Fe(CO) 5 , Ni(CO) 4 and CoNO(CO) 3 is carried out with 11.6 and 11.8 cV phoions, all the ligands are removed in a single step; excess energy is removed by the metal atom as electronic excitation. Compar
Publikováno v:
Journal de Chimie Physique. 73:237-245
L'irradiation dans l’UV lointain de SO2 disperse a 5 K en matrices d’argon, d’azote et de CF4 conduit a la seule emission de phosphorescence de l’etat a3 B1 vibrationnellement relaxe de SO2 . Les spectres de phosphorescence, inde- pendants de
Autor:
C. Lalo, Catherine Vermeil
Publikováno v:
Journal de Chimie Physique. 77:131-136
La constante de vitesse a 298 K de la reaction d'oxydation de CH3 OH par O (3 P) est determinee pour la premiere fois. Les atomes O (3 P) sont produits par photolyse pulsee de O2 en systeme dynamique et leur declin est suivi par photometrie de resona
Publikováno v:
The Journal of Chemical Physics. 66:2656-2659
The vuv photodissociation of OCS in an argon matrix at 5 K has been shown to yield S(1S) atoms. The S(1S –1D) emission is observed only during the irradiation and does not appear when CS2 is photolyzed under the same conditions. However, in both ca
Autor:
Catherine Vermeil, Jeannine Masanet
Publikováno v:
Journal de Chimie Physique. 74:795-798
Publikováno v:
Chemical Physics Letters. 73:315-318
We have investigated the emission of a CO2 molecule isolated in an Ar matrix at 4.7 K in the spectral region between 350 and 550 nm. This emission is a continuum with a lifetime of 570 ms. We assign it to the transition from the lowest triplet state
Publikováno v:
Chemical Physics. 33:123-130
The lifetime of the b 1 Σ + state of the NH radical is measured again and its radiative Einstein coefficient is calculated. By measuring the ND lifetime, and assuming the same Einstein coefficient for both b → X transitions, the nonradiative decay