Zobrazeno 1 - 10
of 23
pro vyhledávání: '"Cassandra P. Lilly"'
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 1, Pp 25-30 (2016)
Three isostructural coordination networks of Ce, Pr, and Nd nitrate with 4,4′-bipyridine N,N′-dioxide (bpydo) are reported, namely poly[[tris(nitrato-κ2O,O′)cerium(III)]-bis(μ2-4,4′-bipyridine N,N′-dioxide-κ2N:N′)], [Ce(NO3)3(C10H8N2O2
Externí odkaz:
https://doaj.org/article/0e19aea79bfb4e4ca16afa310bb1cd14
Publikováno v:
Organometallics. 39:388-396
Direct insertion of CO and isocyanides, RNC, into Re–R bonds results in high-oxidation-state acyl and iminoacyl complexes that can be treated with an electrophile to generate rare examples of rheni...
Publikováno v:
Acta Crystallographica Section E, Vol 66, Iss 9, Pp m1156-m1157 (2010)
The title one-dimensional coordination network, {[Eu2(NO3)6(C10H8N2O2)3]·2CH2Cl2}n, is isostructural with the previously reported Tb and Tl coordination networks and to its Gd analog. The EuIII cation is coordinated in a distorted tricapped trigonal
Externí odkaz:
https://doaj.org/article/881042944c864f06b1ae742c53fadd5b
Publikováno v:
Organometallics. 35:3530-3537
Several oxorhenium complexes bearing an SSS pincer ligand were isolated and characterized, and their reactivity with carbon monoxide was explored. The corresponding oxorhenium(V) acyl derivatives were also isolated and characterized. Carbonylation re
Publikováno v:
Organometallics. 35:3060-3068
Computational studies (M06) have been performed in synergy with experimental studies to show that the thermodynamics for insertion of CO into an oxorhenium–hydride bond to form a formyl ligand is favorable despite conventional wisdom to the contrar
Publikováno v:
Organometallics. 35:2822-2829
Several oxorhenium hydride complexes with chelating diamidopyridine (DAP), diamidoamine (DAAm), and 2-mercaptoethyl sulfide (SSS) groups have been isolated and characterized. Adduct formation is observed when the DAP complex 1a is treated with the Le
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 1, Pp 25-30 (2016)
Acta Crystallographica Section E: Crystallographic Communications
Acta Crystallographica Section E: Crystallographic Communications
The crystal structures of poly[bis(μ2-4,4′-bipyridine N,N′-dioxide-κ2 O:O′)trinitratocerium(III)] and its isostructural praseodymium and neodymium analogues feature a 44 grid-like layered structure with interdigitation of layers promote
Publikováno v:
Organometallics. 34:3152-3158
The complexes [(DAAm)Re(O)(R)] [DAAm = N,N-bis(2-arylaminoethyl)methylamine; aryl = C6F5], 1, R = Me; 3a–d (R = benzyl, a; 4-methylbenzyl, b; 4-fluorobenzyl, c; 4-methoxybenzyl, d); and 4, R = Ph, were synthesized. CO insertion into the Re–R bond
Publikováno v:
ACS Catalysis. 3:2421-2429
Cp*Ir(III) complexes have been shown to catalyze the oxidative coupling of benzoic acids with alkynes in methanol at 60 °C to form a variety of isocoumarins. The use of AgOAc as an oxidant was required to facilitate significant product formation. Al
Publikováno v:
Organometallics. 31:4295-4301
A series of oxorhenium alkyl, phenyl, and vinyl complexes of the form [(DAP)Re(O)(R)] (R = aryl, vinyl, alkyl) was reported, and their reactivity with CO was examined. The methyl complex 5a reacts with CO at a significantly faster rate (2.5 h) than t