Výsledky vyhledávání - "Casper M. Macaulay"

A comparative analysis of hydrosilative amide reduction catalyzed by first-row transition metal (Mn, Fe, Co, and Ni) N-phosphinoamidinate complexes

Autor: Orson L. Sydora, Takahiko Ogawa, Laura Turculet, Robert McDonald, Casper M. Macaulay, Mark Stradiotto

Publikováno v: Dalton Transactions. 48:9581-9587

A comparative study of the performance of (PN)M(N(SiMe3)2) (M = Mn, Fe, Co, and Ni) pre-catalysts supported by N-phosphinoamidinate ligation, as well as M(N(SiMe3)2)n (M = Li, Na, K, Mn, Fe, and Co) pre-catalysts, in the hydrosilative reduction of se

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2dbf1049ad0af36eb42cde4caeaed308
https://doi.org/10.1039/c8dt04221g

Zobrazit plný text záznamu

Synthetic investigations of low-coordinate (N-phosphino-amidinate) nickel chemistry: agostic alkyl complexes and benzene insertion into Ni-H

Autor: Laura Turculet, Daniel H. Ess, Mark Stradiotto, Madhu Samolia, Michael J. Ferguson, Orson L. Sydora, Casper M. Macaulay

Publikováno v: Dalton transactions (Cambridge, England : 2003). 49(15)

Treatment of (PN)NiX (X = NHdipp or OtBu; PN = N-phosphinoamidinate ligand) with Me2PhSiH in benzene solvent afforded the crystallographically characterized, antifacial-coordinated, dinuclear species 1, the formation of which corresponds to the hithe

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3fe74d49cafcb1037f42eb8b330888f9
https://pubmed.ncbi.nlm.nih.gov/32215397

Zobrazit plný text záznamu

Alkene Isomerization–Hydroboration Catalyzed by First-Row Transition-Metal (Mn, Fe, Co, and Ni) N-Phosphinoamidinate Complexes: Origin of Reactivity and Selectivity

Autor: Michael D. Lumsden, Daniel H. Ess, Laura Turculet, Michael J. Ferguson, Takahiko Ogawa, Steven M. Bischof, Jack T. Fuller, Robert McDonald, Orson L. Sydora, Casper M. Macaulay, Mark Stradiotto, Doo-Hyun Kwon, Samantha J. Gustafson

Publikováno v: ACS Catalysis. 8:9907-9925

We describe the results of our combined experimental and computational investigation of structurally analogous (N-phosphinoamidinate)metal(N(SiMe3)2) precatalysts ((PN)M; M = Mn2+, Fe2+, Co2+, and Ni2+; d5–d8) in the isomerization–hydroboration o

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a92214bd4eebd61e0de595c49d2efb32
https://doi.org/10.1021/acscatal.8b01972

Zobrazit plný text záznamu

Dehydrogenative B−H/C(sp 3 )−H Benzylic Borylation within the Coordination Sphere of Platinum(II)

Autor: Laura Turculet, Colin M. Kelly, Mark Stradiotto, Daniel H. Ess, Michael J. Ferguson, Steven M. Bischof, Robert McDonald, Orson L. Sydora, Casper M. Macaulay, Jack T. Fuller

Publikováno v: Angewandte Chemie International Edition. 56:6312-6316

The first examples of stoichiometric dehydrogenative B-H/C(sp3 )-H benzylic borylation reactions, which are of relevance to catalytic methylarene (di)borylation, are reported. These unusual transformations involving a (κ2 -P,N)Pt(η3 -benzyl) comple

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::96e7a043317cef801dde31293b8db33d
https://doi.org/10.1002/anie.201700857

Zobrazit plný text záznamu

Utility of a heterogeneous palladium catalyst for the synthesis of a molecular semiconductor via Stille, Suzuki, and direct heteroarylation cross-coupling reactions

Autor: Gregory C. Welch, Jenny S. J. McCahill, Arthur D. Hendsbee, Seth M. McAfee, Casper M. Macaulay

Publikováno v: RSC Advances. 5:26097-26106

The commercially available silica-supported heterogeneous catalyst SiliaCat® DPP-Pd has proven to be highly active, robust, and reusable for the synthesis of a thiophene–phthalimide-based molecular semiconductor under microwave-irradiation reactio

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d0af385f53a342eea79aba48da1ab82a
https://doi.org/10.1039/c5ra02468d

Zobrazit plný text záznamu

Dehydrogenative B-H/C(sp

Autor: Colin M, Kelly, Jack T, Fuller, Casper M, Macaulay, Robert, McDonald, Michael J, Ferguson, Steven M, Bischof, Orson L, Sydora, Daniel H, Ess, Mark, Stradiotto, Laura, Turculet

Publikováno v: Angewandte Chemie (International ed. in English). 56(22)

The first examples of stoichiometric dehydrogenative B-H/C(sp

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::c4c7d68f3a5086b85cde774985a4ec15
https://pubmed.ncbi.nlm.nih.gov/28370808

Zobrazit plný text záznamu

Synthesis of an H-aggregated thiophene–phthalimide based small molecule via microwave assisted direct arylation coupling reactions

Autor: Gregory C. Welch, Casper M. Macaulay, Arthur D. Hendsbee

Publikováno v: Dyes and Pigments. 102:204-209

We report on the design, optimized synthesis, and characterization of a thiophene–phthalimide based small molecule. We show that microwave irradiation is a useful technique to accelerate direct arylation cross-coupling reactions, and that the thiop

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5d4f3f53bb855b30b74bb96ff5d1376b
https://doi.org/10.1016/j.dyepig.2013.10.046

Zobrazit plný text záznamu

Phthalimide–thiophene-based conjugated organic small molecules with high electron mobility

Autor: Gregory C. Welch, Arthur D. Hendsbee, Ian G. Hill, Lesley R. Rutledge, Ala'a F. Eftaiha, Casper M. Macaulay, Jon-Paul Sun

Publikováno v: J. Mater. Chem. C. 2:2612-2621

A series of low-cost phthalimide end-capped oligothiophene small molecules with variations to the terminal alkyl chain and number of thiophene units in the conjugated core have been synthesized and investigated. All molecules exhibit H-aggregation in

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::53d8bd9ddce22041d39996ffd873df95
https://doi.org/10.1039/c3tc32497d

Zobrazit plný text záznamu

Vyhledávací nástroje:

Upřesnit hledání