Experimental and DFT Study of the [AuAr(AsPh3)]-Catalyzed cis/trans Isomerization of [PdAr2(AsPh3)2] (Ar = C6F5 or C6Cl2F3): Alternative Mechanisms and Its Switch upon Pt for Pd Substitution

Autor: Villar, Pedro, Pérez Temprano, Mónica H., Casares González, Juan Ángel, Álvarez, Rosana, Espinet Rubio, Pablo

Publikováno v: UVaDOC: Repositorio Documental de la Universidad de Valladolid
Universidad de Valladolid
UVaDOC. Repositorio Documental de la Universidad de Valladolid
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Producción Científica
The aryl transmetalation processes between cis-[PdRf2(AsPh3)2] (Rf = C6Cl2F3) and [AuPf(AsPh3)] (Pf = C6F5) has been studied experimentally and by DFT calculations. Aryl exchange with or without isomerization of the Pd ge

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::3370513d0f6f4ba1146bdbfb62e6c58a
http://uvadoc.uva.es/handle/10324/42910

[Cu(C6Cl2F2)(tht)]4: An Extremely Efficient Catalyst for the Aryl Scrambling between Palladium Complexes

Autor: Pérez Iglesias, María, Lozano Lavilla, Olmo, Casares González, Juan Ángel

Publikováno v: UVaDOC. Repositorio Documental de la Universidad de Valladolid
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The copper compound [Cu(C6Cl2F3)(tht)]4 (1) (tht: tetrahydrothiophene) is an excellent catalyst for the trans-to-cis isomerization of complexes [PdAr2(tht)2](Ar: fluoroaryl) and also for the exchange of aryls between those palladium complexes. Herein

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::eb07ee8890a09d60b388acc1889a83c5
https://doi.org/10.1021/acs.organomet.8b00885

Cross Alkyl-Aryl Versus Homo Aryl-Aryl Coupling in Pdcatalyzed Coupling of Alkyl-Gold(I) and Aryl-X (X = Halide)

Autor: Carrasco Fernández, Desiré, Pérez Temprano, Mónica H., Casares González, Juan Ángel, Espinet Rubio, Pablo

Publikováno v: UVaDOC. Repositorio Documental de la Universidad de Valladolid
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Producción Científica
Experiments on palladium catalyzed cross-coupling of [AuMe(PPh3)] with aryl iodides show that Ar–Ar homocoupling products are the main product or an abundant byproduct of the reaction. The percentage of cross-coupling p

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::289299023b752950595fb6326e79adce
https://doi.org/10.1021/om500446x

Reacciones de inserción de CO2 catalizadas por complejos de cobre

Autor: Martín Calderón, Gonzalo

Publikováno v: UVaDOC. Repositorio Documental de la Universidad de Valladolid
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Este trabajo trata sobre metodologías catalíticas basadas en reacciones de inserción de CO2 en enlaces Cu-C. A través de diversos trabajosexperimentales y computacionales, se analizan las diferentes reacciones a través de las cuales se pueden fo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::9bb9df5c8cd64fb994e0691fb1e2b004

The transmetalation step in Pd-catalyzed processes: understanding the role of the classical nucleophile, the ligands and the synthetic potential of a third metal

Autor: Pozo del Valle, Juan del

Publikováno v: UVaDOC. Repositorio Documental de la Universidad de Valladolid
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The transmetalation step of Pd-catalyzed reactions is studied in-depth in this Doctoral Thesis. New bimetallic systems based on the Au/Pd and the Cu/Pd couple have been developed in the context of the Stille reaction and the Hiyama reaction that are

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::44de40edde7b5a1d3673fe75c7c8ba8b
https://doi.org/10.35376/10324/39306