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Small Particle Size Magnesium in One-pot Grignard-Zerewitinoff-like Reactions under Mechanochemical Conditions:On the Kinetics of Reductive Dechlorination of Persistent Organic Pollutants (POP's)

Autor: Ruck, Wolfgang, Birke, Volker, Schütt, Christine

Publikováno v: Ruck, W, Birke, V & Schütt, C 2009, Small Particle Size Magnesium in One-pot Grignard-Zerewitinoff-like Reactions under Mechanochemical Conditions : On the Kinetics of Reductive Dechlorination of Persistent Organic Pollutants (POP's) . in C L Geiger & K M Carvalho-Knighton (eds), Environmental Applications of Nanoscale and Microscale Reactive Metal Particles . vol. 1027, ACS Symposium Series, no. 1027, ACS Publications, pp. 39-54 . DOI: 10.1021/bk-2009-1027.ch003
Ruck, W, Birke, V & Schütt, C 2009, Small Particle Size Magnesium in One-pot Grignard-Zerewitinoff-like Reactions under Mechanochemical Conditions : On the Kinetics of Reductive Dechlorination of Persistent Organic Pollutants (POP's) . in C L Geiger & K M Carvalho-Knighton (eds), Environmental Applications of Nanoscale and Microscale Reactive Metal Particles . vol. 1027, ACS Symposium Series, no. 1027, ACS Publications, pp. 39-54 . https://doi.org/10.1021/bk-2009-1027.ch003

Small particle size base metals are produced in a ball mill mechanochemical (MC) reactor. During ongoing milling they react at room temperature simultaneously and in a single process step, to rapidly, and highly selectively reduce by dechlorination p

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