Asymmetric β-Aminoethylation of Ketones and Nitriles with Tosylaziridines Employing the SAMP-Hydrazone Method

Autor: Dieter Enders, Gerhard Raabe, Carsten F. Janeck

Publikováno v: European Journal of Organic Chemistry. 2000:3337-3345

The nucleophilic ring-opening of tosylaziridines with chiral aza-enolates is reported. The SAMP-/ RAMP-hydrazones 1a−h derived from aldehydes or ketones were reacted with tosylaziridine 2a to give the β-aminoethylated hydrazones 3a−h with good d

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b84a90b1626e80fd3798d2c90f12c70e
https://doi.org/10.1002/1099-0690(200010)2000:19<3337::aid-ejoc3337>3.0.co

ChemInform Abstract: The SAMP-/RAMP-Hydrazone Methodology in Asymmetric Synthesis

Autor: Carsten F. Janeck, Andreas Job, Wolfgang Bettray, Dieter Enders, René Peters

Publikováno v: ChemInform. 33

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b618863c44e7f69826ba54e5729885fd
https://doi.org/10.1002/chin.200230277

Asymmetric Total Synthesis of the 1- e pi -Aglycon of the Cripowellins A and B

Autor: Gerhard Raabe, Carsten F. Janeck, Achim Lenzen, Kelly Catlin, Jan Runsink, Michael Backes, Marie-Isabelle Lannou, Dieter Enders

Publikováno v: Journal of Organic Chemistry
Journal of Organic Chemistry, American Chemical Society, 2005, 70 (25), pp.10538-10551. ⟨10.1021/jo0518093⟩

[structure: see text] The unusual [5.3.2]-bicyclic structure of the insecticidal Amaryllidaceae alkaloids cripowellin A (1) and B (2) has been synthesized for the first time via a sequence of Sharpless dihydroxylation, ring-closing metathesis, and in

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::81f209272ce879ffe5c5e4212a05350f
https://hal.archives-ouvertes.fr/hal-02371135