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Publikováno v:
Inorganic Chemistry. 29:1679-1682
A series of group V transition-metal (trimethylsily)imido compounds has been synthesized in which the NSiMe 3 groups derive from hexamethyldisilazane. Reaction of MCl 5 with 2 equiv of NH(SiMe 3 ) 2 produces [M(NSiMe 3 )Cl 3 (NH 2 SiMe 3 )] 2 (M=Nb,
Publikováno v:
ChemInform. 21
A series of group V transition-metal (trimethylsily)imido compounds has been synthesized in which the NSiMe 3 groups derive from hexamethyldisilazane. Reaction of MCl 5 with 2 equiv of NH(SiMe 3 ) 2 produces [M(NSiMe 3 )Cl 3 (NH 2 SiMe 3 )] 2 (M=Nb,