Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Carolien J. den Reijer"'
Publikováno v:
Organometallics. 20:2982-2989
Reactions of [Ru(arene)(MeO−Biphep)](SbF6)2 (arene = p-cymene, 4, or benzene, 5; MeO−Biphep = (6,6‘-dimethoxybiphenyl-2,2‘-diyl)bis(diphenylphosphine)) with several terminal acetylene compounds lead to products derived from cyclometalation of
Publikováno v:
Canadian Journal of Chemistry. 79:693-704
A series of cationic and dicationic Ru-arene complexes with Binap (1a) and MeO-Biphep (1b) have been prepared. 13C NMR studies are shown to be useful in connection with recognising the 6e-bonding mode of 1a and 1b in the dications [Ru(1a or 1b)(η6-a
Publikováno v:
Organometallics. 19:309-316
Reaction of Ru(OAc)2(1 or 2), 1 = racemic Binap, or 2 = racemic MeO−Biphep, with wet CF3SO3H in 1,2-dichloroethane at 363 K results in P−C bond breaking to afford the cationic triflates [Ru(CF3SO3)(6‘-diphenylphosphino-1-naphthyl)(PPh2OH)](CF3S
Publikováno v:
Organometallics. 17:5213-5215
Reaction of Ru(OAc)2(MeO-Biphep) (MeO-Biphep = 6,6‘-dimethoxybiphenyl-2,2‘-diylbis(diarylphosphine)) with 2 equiv of HBF4 in CH2Cl2 cleaves the MeO-Biphep. Products contain the exotic chelate ligand (aryl)2POB(OH)F2 (aryl = phenyl, p-tolyl, 3,5-d