Výsledky vyhledávání - "Carmen Antuña‐Hörlein"

Activation Barriers for Cobalt(IV)-Centered Reductive Elimination Correlate with Quantified Interatomic Noncovalent Interactions

Autor: Jean-Pierre Djukic, Yann Cornaton, Lucas Loir-Mongazon, Carmen Antuña-Hörlein, Christophe Deraedt

Publikováno v: Synlett. 34:1169-1173

In this joint theoretical and experimental study, an analysis of weak interligand noncovalent interactions within Co(IV) [Cp*Co(phpy)X]+ cobaltacycles (phpy = 2-phenylenepyridine, κ C,N ) was carried out by using the independent gradient model/intri

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7a76c4a3cb63de910c69204ce31a3cb6
https://doi.org/10.1055/a-1937-9296

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Cobalt Nanoparticles Formed upon Reaction of Cp*Co(III) Metallacycles with Na[BHEt 3 ] Show Catalytic Activity in the Hydrosilylation of Aryl Ketones, Aldehydes and Nitriles

Autor: Carmen Antuña‐Hörlein, Fule Wu, Christophe Deraedt, Corinne Bouillet, Jean‐Pierre Djukic

The reactivity of the 2-phenylpyridine-derived [Cp*CoI(phpy-κC,N)] metallacycle towards Et3SiH and hydrides was evaluated. The treatment of the same Co(III) complex with Na[BHEt3] resulted in its decomposition into cobalt nanoparticles. The hydride-

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e6bb656b4d0ab7a60d46e9fbeb51af90
Wiley Online Library

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