Zobrazeno 1 - 10
of 14
pro vyhledávání: '"Carlos Perez-Balado"'
Publikováno v:
The Journal of Organic Chemistry. 75:3037-3046
Carbon dioxide can be used as a convenient carbonylating agent in the synthesis of 2-oxazolidinones, 2-oxazinones, and cyclic ureas. The transient carbamate anion generated by treating a primary or secondary amine group in basic media can be activate
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b585f4e928cba265d3f9d21ecb4e9234
https://doi.org/10.1021/jo100268n
https://doi.org/10.1021/jo100268n
Autor:
Wim Albert Alex Aelterman, Dominic Ormerod, Albert Willemsens, Carlos Perez-Balado, Narda Mertens
Publikováno v:
Organic Process Research & Development. 11:237-240
A practical and scaleable synthesis of 2-chloro-5-(pyridin-2-yl) pyrimidine, an intermediate in the synthesis of a selective PDE-V inhibitor, was developed. A Negishi cross-coupling between the in situ prepared 2-pyridylzinc chloride and 5-iodo-2-chl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d014898583a6c8ff0e850f2a759b7b60
https://doi.org/10.1021/op060241c
https://doi.org/10.1021/op060241c
Autor:
Carlos Perez‐Balado, István E. Markó
Publikováno v:
Tetrahedron. 62:2331-2349
syn-Hydroalumination of 2,4,6-triisopropylphenylselanyl-1-alkynes with DIBAL-H followed by AI/I exchange with 1, afforded exclusively (E)-1-iodo-1-selenoalkenes in good yields. 1-Iodo-1-selenopropene 10 proved to be a convenient 1.1 dianion equivalen
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7e5c62773ddce9da5fe6358e4400acdf
https://doi.org/10.1016/j.tet.2005.12.005
https://doi.org/10.1016/j.tet.2005.12.005
Autor:
Carlos Perez‐Balado, István E. Markó
Publikováno v:
Tetrahedron Letters. 46:4887-4890
Racemic tetrahydropyran 3 was efficiently synthesised from allylsilane 6 and aldehyde 7 via an intramolecular Sakurai cyclisation. In a single step, the relative configuration of three chiral centres was established. Allylsilane 6 was readily assembl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b039629ace9ac2ae14dc4db0de15e2ec
https://doi.org/10.1016/j.tetlet.2005.05.054
https://doi.org/10.1016/j.tetlet.2005.05.054
Autor:
Koen De Smet, Dominic Ormerod, Tom Govaerts, Dominique Depré, Inge Schorpion, Andras Horvath, and Dirk Van den Heuvel, Carlos Perez-Balado
Publikováno v:
Organic Process Research & Development. 9:356-359
In-line FTIR was applied as a suitable PAT (process analytical technology) to monitor and control the enolate formation step in the one-carbon homologation process of a 4-methylcoumarin with chloromethyl pivalate. The techniques to determine the endp
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::75a9d686efc66a5c713876bd7ece6731
https://doi.org/10.1021/op049787u
https://doi.org/10.1021/op049787u
Publikováno v:
ChemInform. 42
The condensation of carbamoyl nitroso compounds, obtained by oxidation of N-hydroxyureas, with amines unexpectedly afforded semicarbazones (aka carbamoyl hydrazones). Although the substitution of the nitrosyl moiety might compete to afford the corres
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4ac858e200758f86885e9e2c0094d20f
https://doi.org/10.1002/chin.201127084
https://doi.org/10.1002/chin.201127084
Publikováno v:
Organic letters. 13(7)
The condensation of carbamoyl nitroso compounds, obtained by oxidation of N-hydroxyureas, with amines unexpectedly afforded semicarbazones (aka carbamoyl hydrazones). Although the substitution of the nitrosyl moiety might compete to afford the corres
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b731ca6c2e17d65c65ffee40a431312f
https://pubmed.ncbi.nlm.nih.gov/21384823
https://pubmed.ncbi.nlm.nih.gov/21384823
Publikováno v:
ChemInform. 42
Treatment of carbamoyl azides with hyrdroxylamine allows a new and convenient access to hydroxyureas.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::21662c39d306846ad3294e9c59e26558
https://doi.org/10.1002/chin.201111057
https://doi.org/10.1002/chin.201111057
Publikováno v:
The Journal of organic chemistry. 75(23)
The carbamoylating agents carbamoyl azides and carbamoyl cyanides (aka cyanoformamides) react with hydroxylamine in different ways, leading in the first case to N-hydroxyureas and, in the case of carbamoyl cyanides, to carbamoyl amidoxime derivatives
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ac2aec6ba0541aa0db526fc9ee515f2e
https://pubmed.ncbi.nlm.nih.gov/21049914
https://pubmed.ncbi.nlm.nih.gov/21049914
Publikováno v:
ChemInform. 41
Carbon dioxide can be used as a convenient carbonylating agent in the synthesis of 2-oxazolidinones, 2-oxazinones, and cyclic ureas. The transient carbamate anion generated by treating a primary or secondary amine group in basic media can be activate
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2daa84b477142c6adfc84bdcca6a41b3
https://doi.org/10.1002/chin.201034049
https://doi.org/10.1002/chin.201034049