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pro vyhledávání: '"Carlos Perez-Arrieta"'
Autor:
J. Armando Lujan-Montelongo, Carolina Silva-Cuevas, Luis A. Polindara-García, Carlos Perez-Arrieta
Publikováno v:
Tetrahedron Letters. 58:2244-2247
A rapid and facile method provides a general route to sulfonyl bromides/chlorides by the oxidation of thiols using NXS – ROH (X = Br,Cl, R = i Pr) as an oxyhalogenation reagent. Control experiments suggest that the alcohol component is the source o
Autor:
Ehecatl Paleo, Carlos Perez-Arrieta, Adabelia Tapia-Pineda, J. Armando Lujan-Montelongo, Carolina Silva-Cuevas
Publikováno v:
Journal of Chemical Education. 93:1470-1474
A simple, microscale experiment was developed with the aim of demonstrating the concept of umpolung in synthetic organic chemistry. Starting from a common alkyl sulfinate, students perform a polarity inversion by performing a Grignard-based sulfoxide