Zobrazeno 1 - 10 of 19 pro vyhledávání: '"Carlos Alvarez Lamsfus"'
1
Akademický článek
Phenylacetylene and Carbon Dioxide Activation by an Organometallic Samarium Complex
Autor: Violaine Goudy, Mathieu Xémard, Simon Karleskind, Marie Cordier, Carlos Alvarez Lamsfus, Laurent Maron, Grégory Nocton
Publikováno v: Inorganics, Vol 6, Iss 3, p 82 (2018)
Small molecule activation is a topic of growing importance and the use of low-valent f-elements to perform these reactions is nowadays well established. The complex Cptt2Sm(thf) (1, Cptt = 1,3-(tBu)2Cp) is shown to activate the alkyne C–H bond of p
Externí odkaz: https://doaj.org/article/894c07115ddd4874b13638f4ef1ce7cc
Zobrazit plný text záznamu
2
Akademický článek
Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides
Autor: Jingzhen Du, Carlos Alvarez-Lamsfus, Elizabeth P. Wildman, Ashley J. Wooles, Laurent Maron, Stephen T. Liddle
Publikováno v: Nature Communications, Vol 10, Iss 1, Pp 1-13 (2019)
Despite the burgeoning nature of uranium–ligand multiple bonding, analogous thorium complexes remain incredibly rare. Here the authors report evidence for a transient thorium–nitride species, which, together with data on parent imido derivatives,
Externí odkaz: https://doaj.org/article/bb7903e68b554b979a100c14040e7390
Zobrazit plný text záznamu
4
Kinetic stabilisation of a molecular strontium hydride complex using an extremely bulky amidinate ligand
Autor: Thomas Sutcliffe, Laurent Maron, Caspar N. de Bruin-Dickason, Cameron Jones, Glen B. Deacon, Carlos Alvarez Lamsfus
Publikováno v: Chemical Communications
Chemical Communications, 2018, 54 (7), pp.786-789. ⟨10.1039/c7cc09362d⟩
International audience; Two extremely bulky amidinate ligands, [RC{N(Dip)}{N(Ar-dagger)}](-) (Dip = 2,6-diisopropylphenyl; Ar-dagger = C6H2{C(H)Ph-2}(2)Pr-i-2,6,4; R = 1-adamantyl (L-Ad), tert-butyl (L-tBu)) have been developed and utilised for the k
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::989b64477830a8c2cc4bcd9ba9519cdd
https://doi.org/10.1039/c7cc09362d
Zobrazit plný text záznamu
5
Synthesis and Reactivity of a Scandium Terminal Hydride: H2 Activation by a Scandium Terminal Imido Complex
Autor: Xianghao Han, Carlos Alvarez Lamsfus, Laurent Maron, Yaofeng Chen, Weiqing Mao, Erli Lu, Li Xiang, Xuebing Leng
Publikováno v: Chemistry - A European Journal. 23:14728-14732
Dihydrogen is easily activated by a scandium terminal imido complex containing the weakly coordinated THF. The reaction proceeds via a 1,2-addition mechanism, which is distinct from -bond metathesis mechanism reported to date for rare-earth metal
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7785c2437b69466ce2bc439dfc65c2fa
https://doi.org/10.1002/chem.201703905
Zobrazit plný text záznamu
6
Reactivity of Ce(iv) imido compounds with heteroallenes
Autor: Carlos Alvarez Lamsfus, Eric J. Schelter, Patrick J. Carroll, Thibault Cheisson, Michael R. Gau, Laurent Maron, Ekaterina Lapsheva
Publikováno v: CHEMICAL COMMUNICATIONS
CHEMICAL COMMUNICATIONS, 2020, 56 (35), pp.4781-4784. ⟨10.1039/c9cc10052k⟩
The reactivity of alkali metal capped Ce(iv) imido compounds [M(DME)2][Ce[double bond, length as m-dash]NArF(TriNOx)] (1-M with M = K, Rb, Cs and ArF = 3,5-bis(trifluoromethyl)phenyl) with CO2 and organic isocyanates has been evaluated. 1-Cs reacted
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::05bf2f31734e6cdf6078a30c1e171396
https://hal.science/hal-03925202
Zobrazit plný text záznamu
7
A complete series of uranium(iv) complexes with terminal hydrochalcogenido (EH) and chalcogenido (E) ligands E = O, S, Se, Te
Autor: Karsten Meyer, Julian Hümmer, Laurent Maron, Frank W. Heinemann, Marinella Mazzanti, Carlos Alvarez Lamsfus, Michael W. Rosenzweig, Andreas Scheurer
Publikováno v: Dalton Transactions
Dalton Transactions, 2019, 48 (29), pp.10853-10864. ⟨10.1039/c9dt00530g⟩
International audience; We here report the synthesis and characterization of a complete series of terminal hydrochalcogenido, U-EH, and chalcogenido uranium(iv) complexes, U equivalent to E (with E = O, S, Se, Te), supported by the ((ArOH)-Ar-Ad,Me)(
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e67b321cd23b7464ed110a856a8ca083
https://pubmed.ncbi.nlm.nih.gov/30950469
Zobrazit plný text záznamu
8
Highly Reactive Scandium Phosphinoalkylidene Complex: C–H and H–H Bonds Activation
Autor: Carlos Alvarez Lamsfus, Weiqing Mao, Xuebing Leng, Laurent Maron, Yaofeng Chen, Li Xiang
Publikováno v: Journal of the American Chemical Society. 139:1081-1084
The first scandium phosphinoalkylidene complex was synthesized and structurally characterized. The complex has the shortest Sc–C bond lengths reported to date (2.089(3) A). DFT calculations reveal the presence of a three center π interaction in th
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0b4b3cfec5746bb2c8395e8fd9d14651
https://doi.org/10.1021/jacs.6b13081
Zobrazit plný text záznamu
9
Metathesis of a UV imido complex: a route to a terminal UV sulfide
Autor: Karsten Meyer, Rory P. Kelly, Marta Falcone, Laurent Maron, Rosario Scopelliti, Carlos Alvarez Lamsfus, Marinella Mazzanti
Publikováno v: Chemical Science
Chemical Science, 2017, 8 (8), pp.5319-5328. ⟨10.1039/c7sc01111c⟩
Chemical Science, The Royal Society of Chemistry, 2017, 8 (8), pp.5319--5328
Chemical Science, The Royal Society of Chemistry, 2017, 8 (8), pp.5319-5328. ⟨10.1039/c7sc01111c⟩
bibtex: ISI:000406103100009 bibtex\location:'THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND',publisher:'ROYAL SOC CHEMISTRY',type:'Article',affiliation:'Mazzanti, M (Reprint Author), Ecole Polytech Fed Lausanne, Inst
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d325b1037c99cce224c6d6bf15823752
https://doi.org/10.1039/c7sc01111c
Zobrazit plný text záznamu

Vyhledávací nástroje:

Upřesnit hledání

Omezení vyhledávání
Plný text Recenzováno Digitální knihovna AV ČR
Zdroje