Zobrazeno 1 - 10
of 62
pro vyhledávání: '"Carl C. Gryte"'
Publikováno v:
Journal of Applied Polymer Science. 96:944-960
Membranes were prepared by the direct and isothermal immersion of polyamide solutions in a formic acid/water bath. A crystalline polycaprolactam homopolymer, nylon 6, and a largely amorphous terpolymer of nylon 6, nylon 66, and nylon 610 were precipi
Publikováno v:
Polymer. 43:4153-4157
A wide variety of commercial polymeric membranes are manufactured by a non-solvent immersion precipitation process, yet the detailed mechanism and kinetics of membrane formation are poorly understood. We have used a confocal microscope, with fluoresc
Publikováno v:
Journal of Polymer Science Part B: Polymer Physics. 37:2079-2092
The equilibrium phase behavior of water (nonsolvent)-DMF (solvent)-PVDF system at 25°C was investigated via both theoretical and experimental approaches. Using binary interaction parameters, χij, obtained previously, the theoretical phase boundarie
Publikováno v:
Polymer. 40:2681-2685
Poly(amic diethyl ester) [PAE] precursors of four different polyimides with various chain rigidities were synthesized and thermally converted to the polyimides in thin films: rodlike poly( p -phenylene pyromellitimide) [PMDA-PDA] and poly(4,4′-biph
Publikováno v:
Polymer. 39:2963-2972
Several photosensitive polyimide (PSPI) precursors were synthesised by the acid/base complexations of conventional poly(amic acid) precursors with photochemically cross-linkable 2-(dimethylamino)ethyl methacrylate. PSPIs in films were prepared from t
Publikováno v:
Journal of Polymer Research. 4:135-138
The possibility of crossing the spinodal boundary by isothermal evaporation in a polymer-1/solvent/polymer-2 system is analyzed. It is found that when the relative diffusional velocity between polymers is zero, the ternary system may be treated as qu
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 34:349-355
Poly(acrylic acid) (PAA) was decarboxylated in aqueous solution as a function of pH and ionic strength in the temperature range 100–350°C. Degradation kinetics were first order with respect to acid functionality. The rate of decarboxylation at hig
Publikováno v:
Journal of Applied Polymer Science. 57:563-572
Mutual diffusivities at 25°C were measured in the range of the polymer weight fraction of 0.15-0.5, using differential interference microscopy. Diffusivities of atactic polystyrene in toluene at 25°C for 0.35-0.5 polymer weight fractions showed goo
Publikováno v:
Journal of Polymer Science Part B: Polymer Physics. 33:505-516
Poly(p-phenylene biphenyltetracarboximide) films with various thicknesses were prepared from the poly(amic acid) precursor by thermal imidization at 230-400°C for 1-10 h under a nitrogen atmosphere. The water sorption in the films was measured at 25
Publikováno v:
Journal of Polymer Science Part B: Polymer Physics. 33:223-235
An analysis is presented, which describes the isothermal ternary diffusion process encountered in the formation of the aliphatic polyamide membranes such as Nylon-66 by direct immersion-precipitation of a polymeric solution in a nonsolvent bath. A ma