Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Carbamates/chemistry"'
Autor:
Mark A. R. de Geus, Henk M. Janssen, Wolter ten Hoeve, Raffaella Rossin, Ron M. Versteegen, Marc S. Robillard
Publikováno v:
Angewandte Chemie-International Edition, 57(33), 10494-10499. Wiley
The bioorthogonal cleavage of allylic carbamates from trans-cyclooctene (TCO) upon reaction with tetrazine is widely used to release amines. We disclose herein that this reaction can also cleave TCO esters, carbonates, and surprisingly, ethers. Mecha
Autor:
Rolf A. T. M. van Benthem, Bart A. J. Noordover, Ellen P. A. van Heeswijk, Shuang Ma, CE Cor Koning, RJ Rafaël Sablong
Publikováno v:
ChemSusChem, 11(1), 149-158. Wiley-VCH Verlag
Here, an isocyanate-free approach to produce polyureas from diamines and dicarbamates as monomers is reported. A side reaction limiting the molecular weight during the diamine/ dicarbamate polymerization, that is, N-alkylation of amine end groups, is
Autor:
Joren Guillaume, Dirk Elewaut, Nora Pauwels, Sandrine Aspeslagh, Dirk M. Zajonc, Serge Van Calenbergh
Publikováno v:
BIOORGANIC & MEDICINAL CHEMISTRY
Alpha-galactosyl ceramide (α-GalCer) is a prototypical synthetic ligand of invariant natural killer T (iNKT) cells. Upon presentation by the MHC class I-like molecule CD1d, this glycolipid stimulates iNKT cells to secrete a vast amount of both pro-i