Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Can-Can Bao"'
Publikováno v:
Communications Chemistry, Vol 4, Iss 1, Pp 1-8 (2021)
Direct conversion of amides to ketones typically requires the use of transition metal catalysts or reactive organometallic reagents. Here the direct alkylation of benzamides with methyl sulfides using LDA as base provides access to thioalkoxyketones.
Externí odkaz:
https://doaj.org/article/6d4e8cd90c004f758c13bed418ccb01b
Publikováno v:
Science China Chemistry. 64:1349-1354
The deprotonative functionalization of toluenes, for their weak acidity, generally needs strong bases, thus leading to the requirement of harsh conditions and the generation of by-products. Direct nucleophilic acyl substitution reaction of amides wit
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fe537e579682f758bd964c3350f16243
https://doi.org/10.1007/s11426-021-1035-5
https://doi.org/10.1007/s11426-021-1035-5
Publikováno v:
Organometallics. 37:4763-4772
N-Heterocyclic carbenes (NHCs) were found to be suitable ligands in Ir-catalyzed intermolecular allylic alkylation reaction. In the presence of a catalyst derived from [Ir(dncot)Cl]2 (dncot = dinaphthocyclooctatetraene) and triazolium salt L7, the al
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9ffba0118681b27dbe349ca4e14f4466
https://doi.org/10.1021/acs.organomet.8b00762
https://doi.org/10.1021/acs.organomet.8b00762