Experimental and Computational Studies of Ruthenium Complexes Bearing Z-Acceptor Aluminum-Based Phosphine Pincer Ligands

Autor: Connie J. Isaac, Cameron I. Wilson, Arron L. Burnage, Fedor M. Miloserdov, Mary F. Mahon, Stuart A. Macgregor, Michael K. Whittlesey

Publikováno v: Isaac, C J, Wilson, C I, Burnage, A L, Miloserdov, F, Mahon, M F, Macgregor, S A & Whittlesey, M K 2022, ' Experimental and Computational Studies of Ruthenium Complexes Bearing Z-Acceptor Aluminum-Based Phosphine Pincer Ligands ', Inorganic Chemistry, vol. 61, no. 50, pp. 20690-20698 . https://doi.org/10.1021/acs.inorgchem.2c03665

Reaction of [Ru(C 6H 4PPh 2) 2(Ph 2PC 6H 4AlMe(THF))H] with CO results in clean conversion to the Ru-Al heterobimetallic complex [Ru(AlMePhos)(CO) 3] (1), where AlMePhos is the novel P-Al(Me)-P pincer ligand (o-Ph 2PC 6H 4) 2AlMe. Under photolytic co

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https://purehost.bath.ac.uk/ws/files/255636611/Whittlesey_Macgregor_revised_MS.pdf