Zobrazeno 1 - 10
of 33
pro vyhledávání: '"Calum R. I. Chisholm"'
Publikováno v:
Nature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
Uniformly distributing nanoparticles on nanofibres can benefit electrocatalysis by increasing surface area, but it is complex. Here the authors use facile, inexpensive, nozzle-free electrospinning to produce dispersed nanoparticles on nanofibres, att
Externí odkaz:
https://doaj.org/article/26feb075cde14ae3bede4208880d26a1
Publikováno v:
Joule. 5:1660-1677
Summary Fuel cells utilize the chemical energy of liquid or gaseous fuels to generate electricity. As fuel cells extend their territory to include heavy-duty vehicles, new demands for proton conductors, a critical component of fuel cells, have emerge
Autor:
Haemin Paik, Dae-Kwang Lim, Calum R. I. Chisholm, Austin B. Plymill, Strahinja K. Zecevic, Sossina M. Haile, Xin Qian
Summary Production of high-purity hydrogen by thermal-electrochemical decomposition of ammonia at an intermediate temperature of 250°C is demonstrated. The process is enabled by use of a solid-acid-based electrochemical cell (SAEC) in combination wi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::073c0a81a6e62d63cc2ccb8f648937fa
https://resolver.caltech.edu/CaltechAUTHORS:20201104-150508413
https://resolver.caltech.edu/CaltechAUTHORS:20201104-150508413
Publikováno v:
Radacsi, N, Campos, F, Chisholm, C & Giapis, K P 2018, ' Spontaneous formation of nanoparticles on electrospun nanofibres ', Nature Communications, vol. 9, 4740, pp. 1-8 . https://doi.org/10.1038/s41467-018-07243-5
Nature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
Nature Communications
Nature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
Nature Communications
We report the spontaneous formation of nanoparticles on smooth nanofibres in a single-step electrospinning process, as an inexpensive and scalable method for producing high-surface-area composites. Layers of nanofibres, containing the proton conducti
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d604d572b16fbe6a892a0fcdaa195e53
https://hdl.handle.net/20.500.11820/2f712b74-7b2d-4305-8c40-32c54ba05f08
https://hdl.handle.net/20.500.11820/2f712b74-7b2d-4305-8c40-32c54ba05f08
Autor:
Dae-Kwang Lim, Calum R. I. Chisholm, Jian Liu, Joseph T. Hupp, Sossina M. Haile, Haemin Paik, S. Pandey
Atomic layer deposition (ALD) has been used to apply continuous Pt films on powders of the solid acid CsH_2PO_4 (CDP), in turn, used in the preparation of cathodes in solid acid fuel cells (SAFCs). The film deposition was carried out at 150 °C using
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7804fc85b9501722eb96a8252df3471d
https://resolver.caltech.edu/CaltechAUTHORS:20180719-110553542
https://resolver.caltech.edu/CaltechAUTHORS:20180719-110553542
Publikováno v:
ECS Transactions. 58:175-181
An electrochemical hydrogen compressor (EHC) based on a solid acid electrolyte is built. The EHC operates at temperatures from 230 to 250 °C. The EHC can be used to separate hydrogen from simulated reformate containing more than 2 % CO. The EHC can
Activity and Evolution of Vapor Deposited Pt-Pd Oxygen Reduction Catalysts for Solid Acid Fuel Cells
Autor:
Gabriel M. Veith, Calum R. I. Chisholm, Thomas A. Zawodzinski, Strahinja K. Zecevic, Alexander B. Papandrew
Publikováno v:
Journal of The Electrochemical Society. 160:F175-F182
The performance of hydrogen fuel cells based on the crystalline solid proton conductor CsH2PO4 is circumscribed by the mass activity of platinum oxygen reduction catalysts in the cathode. Here we report on the first application of an alloy catalyst i
Autor:
Mustafa M. Özer, Strahinja K. Zecevic, Alexander B. Papandrew, Ramez A. Elgammal, Calum R. I. Chisholm
Publikováno v:
Chemistry of Materials. 23:1659-1667
We demonstrate cathodes for solid acid fuel cells fabricated by vapor deposition of platinum from the metalorganic precursor Pt(acac)_2 on the solid acid CsH_(2)PO_4 at 210 °C. A network of platinum nanoparticles with diameters of 2−4 nm serves as
Publikováno v:
Chemistry of Materials. 22:1186-1194
A new series of compounds with general chemical formula Ba_(3−x)K_(x)H_(x)(PO_4)_2 has been successfully prepared. This particular stoichiometry was targeted as a candidate solid-state proton conductor because of its anticipated structural similari
Publikováno v:
Faraday Discuss.. 134:17-39
The compound CsH2PO4 has emerged as a viable electrolyte for intermediate temperature (200-300 degrees C) fuel cells. In order to settle the question of the high temperature behavior of this material, conductivity measurements were performed by two-p