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Akademický článek
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Publikováno v:
Coordination Chemistry Reviews. 276:97-111
Tc(VII) and Re(VII) trioxo complexes are currently arousing interest because of their potential use as radiopharmaceuticals due to their hydrophilic character and stability in a biological environment. The radioactive isotopes Tc-99m and Re-188 are r
Publikováno v:
Coordination Chemistry Reviews. 276:97-111
Tc(VII) and Re(VII) trioxo complexes are currently arousing interest because of their potential use as radiopharmaceuticals due to their hydrophilic character and stability in a biological environment. The radioactive isotopes Tc-99m and Re-188 are r
Akademický článek
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K zobrazení výsledku je třeba se přihlásit.
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Autor:
Teresa M. Santos, João Madureira
Publikováno v:
Repositório Científico de Acesso Aberto de Portugal
Repositório Científico de Acesso Aberto de Portugal (RCAAP)
instacron:RCAAP
Repositório Científico de Acesso Aberto de Portugal (RCAAP)
instacron:RCAAP
Several ruthenium(II)-chloro-dimethylsulfoxide complexes with formulae [RuCl2(DMSO)(k(3)-L-1)] or [RuCl(DMSO)(k(4)-L-2)](+), where L-1=[9]aneS(3) (2) or ttbt (5) and L-2=[12]aneS(4) (3), [14]aneS(4) (4) or [14]aneN(4) (6), have been synthesized from
Publikováno v:
The Journal of Organic Chemistry. 61(9):3093-3105
Synthetic methodology is given for the preparation of two different types of thiocrown ethers from optically pure 1,1'-binaphthalene-2,2'-diol (10). The conceptually simplest approach starts from optically pure 10 itself, which is alkylated (4 equiv
Autor:
H. Thijs Stock, Richard M. Kellogg
Publikováno v:
The Journal of Organic Chemistry. 61:3093-3105
Synthetic methodology is given for the preparation of two different types of thiocrown ethers from optically pure 1,1'-binaphthalene-2,2'-diol (10). The conceptually simplest approach starts from optically pure 10 itself, which is alkylated (4 equiv
Autor:
M.C. Feiters, J. Schoonman, H. Brussaard, Huub Kooijman, Anthony L. Spek, F.B.G. Benneker, N. Veldman, C.F. Van Nostrum, Roeland J. M. Nolte
Publikováno v:
Inorganic Chemistry, 35, 959-969. Amer. Chemical Soc.
Inorganic Chemistry 35(4), 959-969. (1996)
Inorganic Chemistry, 35, 4, pp. 959-969
Inorganic Chemistry 35(4), 959-969. (1996)
Inorganic Chemistry, 35, 4, pp. 959-969
The synthesis of novel magnesium, copper, and metal-free porphyrazines, peripherally substituted with dithia-7-crown-2 (MPz(7)), dithia-15-crown-5 (MPz(15)), and dithia-18-crown-6 (MPz(18)) macrocycles is reported. These compounds are prepared starti
Publikováno v:
Inorganic Chemistry. 33(11):2448-2452
Cyclization of 3-thiapentane-1,5-dithiol (4) as its cesium dithiolate with 1,3-dichloropropanone (1) gives in 72% yield the cyclic thioether 3,6,9-trithiadecanone (C7H12OS3, 5). Crystals are white. Crystal data for 5 at 130 K: monoclinic, space group
Autor:
J. J. H. Edema, H. Thijs Stock, Wilberth J. J. Smeets, Anthony L. Spek, J. Buter, Richard M. Kellogg
Publikováno v:
Tetrahedron, 49(20), 4355-4364. PERGAMON-ELSEVIER SCIENCE LTD
Reaction of a dithiol with B(OH)3 and base in MeOH followed by reaction with xylylene dibromides proceeds selectively to give the corresponding ortho, meta or para-cyclophanes in good yield (70-86 %). The syntheses of examples of all three types of b