Zobrazeno 1 - 9 of 9 pro vyhledávání: '"CLIVE B. C. BOYCE"'
1
The phosphorus trichloride–oxygen–olefin reaction: conformation and elimination studies on products derived from 1-chloro-2-fluoro- and 1,2-difluoro-ethylene
Autor: Ian R. Ager, Lawrence D. Phillips, Shirley B. Webb, Clive B. C. Boyce
Publikováno v: J. Chem. Soc., Perkin Trans. 1. :1644-1650
The reaction of phosphorus trichloride and oxygen with fluoro-olefins gives mixtures containing phosphoric and phosphonic dichlorides together with C–C cleavage products. In a wide range of compounds of the type (RO)2P-(O)·CHX·CHYCl, including pr
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::fa88e9986b794abecb6583936280c25d
https://doi.org/10.1039/p19740001644
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2
Re-examination of the vinyl chloride–phosphorus trichloride–oxygen reaction: an example of direct formation of a phosphate derivative from an olefin
Autor: Clive B. C. Boyce, Shirley B. Webb
Publikováno v: J. Chem. Soc. C. :3987-3990
Contrary to previous reports, the reaction of vinyl chloride with phosphorus trichloride and oxygen gives as the main products a 1·7 : 1 mixture of Cl2P(:O)·O·CHCl·CH2Cl and Cl2P(:O)·CHCl·CH2Cl; the former has been incorrectly assigned the stru
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::25953f2dd5d97c2708fca8b027444699
https://doi.org/10.1039/j39710003987
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3
Reaction of trans-1,2-dichloroethylene with phosphorus trichloride–oxygen: the direct formation of a phosphate derivative from an olefin
Autor: Clive B. C. Boyce, Shirley B. Webb
Publikováno v: J. Chem. Soc. C. :1613-1615
The reaction of trans-1,2-dichloroethylene with phosphorus trichloride–oxygen gives Cl2P(:O)·O·CHCl·CHCl2 as the major product (ca. 40% yield) and not the phosphonyl dichloride, Cl2P(:O)·CHCl·CHCl2, as previously reported. This is the first ex
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::588644fdba150f8ef8f8bcea41b60a27
https://doi.org/10.1039/j39710001613
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9
Determination of stereochemistry of vinyl phosphates from proton nuclear magnetic resonance chemical shifts
Autor: Paul A. Worthington, Shirley B. Webb, Clive B. C. Boyce, Lawrence Phillips
Publikováno v: Journal of the Chemical Society, Perkin Transactions 1. :2881
Studies of a wide range of structures R1R2P(X)·O·CYCHW (Y = H, Me, or Ph) indicate that in any pair of isomers the proton cis to the phosphoryl group resonates to low field of the corresponding trans-proton. Reinterpretation of published data sugge
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e1217d851019cc902ec1eff095e15efa
https://doi.org/10.1039/p19730002881
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