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Vibrational Circular Dichroism Detects Symmetry Breaking due to Conformational Mobility in C2-Symmetry Chiral Molecules and Provides Further Insight into Inter-Chromophoric Interactions

Autor: Giuseppe Mazzeo, Sergio Abbate, Stefan E. Boiadjiev, David A. Lightner, Giovanna Longhi

Publikováno v: Symmetry, Vol 12, Iss 11, p 1752 (2020)

Bicyclo[3.3.1]nonane-2,6-dione (1) and bicyclo[3.3.1]nona-3,7-diene-2,6-dione (2) have been examined by vibrational circular dichroism (VCD), which, as for most C2-symmetric systems, exhibits strong VCD signals. In the case of 2, VCD signals are stro

Externí odkaz: https://doaj.org/article/87a441f2bb264f408540c3203452f0eb

Vibrational Circular Dichroism Detects Symmetry Breaking due to Conformational Mobility in C2-Symmetry Chiral Molecules and Provides Further Insight into Inter-Chromophoric Interactions

Autor: David A. Lightner, Giovanna Longhi, Stefan E. Boiadjiev, Giuseppe Mazzeo, Sergio Abbate

Publikováno v: Symmetry, Vol 12, Iss 1752, p 1752 (2020)
Symmetry
Volume 12
Issue 11
Symmetry (Basel) 12 (2020): 1752-1–1752-13. doi:10.3390/sym12111752
info:cnr-pdr/source/autori:Mazzeo, Giuseppe; Abbate, Sergio; Boiadjiev, Stefan E.; Lightner, David A.; Longhi, Giovanna/titolo:Vibrational Circular Dichroism Detects Symmetry Breaking due to Conformational Mobility in C-2-Symmetry Chiral Molecules and Provides Further Insight into Inter-Chromophoric Interactions/doi:10.3390%2Fsym12111752/rivista:Symmetry (Basel)/anno:2020/pagina_da:1752-1/pagina_a:1752-13/intervallo_pagine:1752-1–1752-13/volume:12

Bicyclo[3.3.1]nonane-2,6-dione (1) and bicyclo[3.3.1]nona-3,7-diene-2,6-dione (2) have been examined by vibrational circular dichroism (VCD), which, as for most C2-symmetric systems, exhibits strong VCD signals. In the case of 2, VCD signals are stro

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2a7d6e4545dd015827acb7b9d2872ef4
https://www.mdpi.com/2073-8994/12/11/1752

A chromo-fluorogenic probe for detecting water traces in aprotic solvents based on C2-symmetry dianthrimide–hydroxide complexes: experimental and theoretical studies

Autor: Johannes Naimhwaka, Veikko Uahengo

Publikováno v: Dalton Transactions. 50:336-345

A C2-symmetry dianthrimide based probe (D) and its hydroxide complex (D-OH) are reported as a chromo-fluorogenic sensor for rapid and sensitive detection of trace amounts of water in polar aprotic solvents. Based on intramolecular charge transfer in

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d122159d748950f9d710b0c0324016e4
https://doi.org/10.1039/d0dt03630g