Zobrazeno 1 - 10
of 20
pro vyhledávání: '"C. Vilbert"'
Publikováno v:
Biochemistry. 59:2289-2298
Cytochrome (cyt) P460 is a c-type monoheme enzyme found in ammonia-oxidizing bacteria (AOB) and methanotrophs; additionally, genes encoding it have been found in some pathogenic bacteria. Cyt P460 is defined by a unique post-translational modificatio
Publikováno v:
Curr Opin Electrochem
Current fuel-cell catalysts for oxygen reduction reaction (ORR) and H(2) oxidation use precious metals and, for ORR, require high overpotentials. In contrast, metalloenzymes perform their respective reaction at low overpotentials using earth-abundant
Autor:
Kyle M. Lancaster, Samantha N. MacMillan, David P. Goldberg, Pierre Moënne-Loccoz, Avery C. Vilbert, Ida M. DiMucci, Jesse B. Gordon
Publikováno v:
J Am Chem Soc
The activation of dioxygen by Fe(II)(Me(3)TACN)(S(2)SiMe(2)) (1) is reported. Reaction of 1 with O(2) at −135 °C in 2-MeTHF generates a thiolate-ligated (peroxo)diiron complex Fe(III)(2)(O(2))(Me(3)TACN)(2)(S(2)SiMe(2))(2) (2) that was characteriz
Publikováno v:
Journal of the American Chemical Society. 141:7046-7055
Reaction of the mononuclear nonheme complex [Fe(II)(CH(3)CN)(N3PyS)]BF(4) (1) with an HNO donor, Piloty’s acid (PhSO(2)NHOH, P.A.), at low temperature affords a high-spin (S = 2) Fe(II)-P.A. intermediate (2), characterized by (57)Fe Mössbauer and
Autor:
David P. Goldberg, Avery C. Vilbert, Pierre Moënne-Loccoz, Kyle M. Lancaster, Maxime A. Siegler, Jesse B. Gordon
Publikováno v:
Journal of the American Chemical Society. 141:3641-3653
The synthesis and characterization of a Co(II) dithiolato complex Co(M(e3)TACN)(S(2)SiMe(2)) (1) is reported. Reaction of 1 with O(2) generates a rare thiolate-ligated cobalt-superoxo species Co(O(2))(M(e3)TACN)(S(2)SiMe(2)) (2) that was characterize
Publikováno v:
Chemical Science. 10:3756-3764
Ammonia oxidizing bacteria (AOB) use the cytotoxic, energetic molecule hydroxylamine (NH2OH) as a source of reducing equivalents for cellular respiration. Despite disproportionation or violent decomposition being typical outcomes of reactions of NH2O
Autor:
Pierre Moënne-Loccoz, Aniruddha Dey, Kyle M. Lancaster, David P. Goldberg, Avery C. Vilbert, Alex M. Confer
Publikováno v:
Angewandte Chemie. 130:13653-13657
A nonheme {FeNO}6 complex, [Fe(NO)(N3PyS)]2+ , was synthesized by reversible, one-electron oxidation of an {FeNO}7 analogue. This complex completes the first known series of sulfur-ligated {FeNO}6-8 complexes. All three {FeNO}6-8 complexes are readil
Autor:
Brendan A.C. Harley, Yi Lu, Avery C. Vilbert, Samantha G. Zambuto, Sara Pedron, Julio F. Serrano
Publikováno v:
MRS Commun
Three-dimensional cultures have exciting potential to mimic aspects of healthy and diseased brain tissue to examine the role of physiological conditions on neural biomarkers as well as disease onset and progression. Hypoxia is associated with oxidati
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::004be7ab7656ffb1cc449d7dbc628de4
Publikováno v:
Proceedings of the National Academy of Sciences. 113:14704-14709
Ammonia oxidizing bacteria (AOB) are major contributors to the emission of nitrous oxide (N2O). It has been proposed that N2O is produced by reduction of NO. Here, we report that the enzyme cytochrome (cyt) P460 from the AOB Nitrosomonas europaea con
Autor:
Gourab Banerjee, Avery C. Vilbert, Hannah M. C. Lant, Shin Hee Lee, Eckhard Bill, Brandon Q. Mercado, Stephen Sproules, Patrick L. Holland, James T. Lukens, Daniël L. J. Broere, Kyle M. Lancaster
Publikováno v:
Chemistry-A European Journal, 24(37), 9417. Wiley
Coordination of redox-active ligands to metals is a compelling strategy for making reduced complexes more accessible. In this work, we explore the use of redox-active formazanate ligands in low-coordinate iron chemistry. Reduction of an iron(II) prec
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9dd33cb2977538d5cb38209cff29b221
https://dspace.library.uu.nl/handle/1874/365251
https://dspace.library.uu.nl/handle/1874/365251