Zobrazeno 1 - 10
of 12
pro vyhledávání: '"C. V. Planta"'
Publikováno v:
Helvetica Chimica Acta. 45:528-541
Four crystalline vitamin A2 isomers, i.e. all-trans, 13-cis, 9-cis, and 9,13-di-cis, as well as the corresponding acids and aldehydes, have been prepared from cis- and trans-dehydro-β-ionylideneacetaldehyde.
Publikováno v:
Helvetica Chimica Acta. 45:541-548
Vitamin A2 acid (m. p. 176–178°) has been prepared by the Wittig reaction of (dehydro-β-ionylidene-ethyl)-triphenylphosphonium bromide and n-butyl β-formyl-crotonate. Reduction of this acid with lithium-aluminium hydride gave a mixture of all-tr
Autor:
C. V. Planta
Publikováno v:
Helvetica Chimica Acta. 45:84-87
The UV. spectra of several isoprenoid compounds measured with a vacuum grating spectrometer are reported. The additivity of the molar extinction coefficients of molecules containing several isolated trisubstituted aliphatic double bonds is shown.
Publikováno v:
Helvetica Chimica Acta. 45:548-561
The physical properties of 6 vitamin A2 isomers are reported and compared with those of the corresponding vitamin A isomers.
Publikováno v:
Helvetica Chimica Acta. 42:1278-1282
It is shown how the proton structure of even complicated naturally occurring molecules can be resolved by high resolution nuclear magnetic resonance. This information is used for the structural elucidation of these molecules.
Publikováno v:
Helvetica Chimica Acta. 45:517-528
Crystalline all-trans-vitamin A2 has been prepared from dehydro-β-C14-aldehyde and the isomeric 3-methyl-pent-2-en-4-yn-1-ols. Two vitamin A2 isomers with Pauling hindrance (11-cis and 11, 13-di-cis) have been synthesized from the same starting mate
Publikováno v:
Helvetica Chimica Acta. 45:2241-2256
Nous decrivons la synthese de quelques derives de la dechlorogriseofulvine et de la dechloro-demethyl-griseofulvine substitues dans le noyau A. Les spectres de resonance magnetique nucleaire se sont reveles tres utiles par la determination des struct
Autor:
C. V. Planta
Publikováno v:
Helvetica Chimica Acta. 44:1444-1446
A precession X ray camera has been built and the dimensions of the elementary cell of the vitamins A, B6 and C have been determined with its aid. The accuracy of molecular weight determination by X ray diffraction is checked as well as the indexing o
Publikováno v:
Helvetica Chimica Acta. 43:2088-2089
The number of isoprene units in quinones with isoprenoid side chains is determined by quantitative NMR-spectrometry.
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