Zobrazeno 1 - 10
of 12
pro vyhledávání: '"C. Scott Eschbach"'
Publikováno v:
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 7:269-278
The Clemmensen reduction is an effective means of converting acyl- and vinylic methylidynetricobalt nona-carbonyl complexes to the corresponding saturated alkylidynetricobalt nonacarbonyl when it is carried out in nonaqueous medium. Diborane in tetra
Publikováno v:
Journal of Organometallic Chemistry. 78:C13-C16
Vinyl-substituted of methylidynetricobalt nonacarbonyl of the type RR′CC(R″)CCo3(CO)9 have been prepared, with vinylic groups CH2 CH, CH2 C(CH)3, Me3SiCHCH and CH3 C(O)CHCH. Reaction of the first two with HPF6 produced the carboniu
Publikováno v:
Journal of the American Chemical Society. 100:4124-4131
Publikováno v:
Journal of the American Chemical Society. 96:1730-1737
Publikováno v:
Journal of Organometallic Chemistry. 104:363-372
The 13 C NMR spectra of (hydroxymethyl)-, (α-hydroxyethyl)- and (α-hydroxybenzyl)cyclobutadieneiron tricarbonyl (in CDCl 3 ) and of their derived carbonium ions (in concentrated H 2 SO 4 ) are reported. The data suggest extensive donation of electr
Autor:
Gary H. Williams, Mara O. Nestle, John E. Hallgren, C. Scott Eschbach, Joseph S. Merola, Dietmar Seyferth
Publikováno v:
Journal of the American Chemical Society. 101:4867-4878
Publikováno v:
Journal of Organometallic Chemistry. 97:C11-C15
Publikováno v:
Journal of the American Chemical Society. 98:6724-6726
Publikováno v:
Journal of the American Chemical Society. 94:2547-2549
Publikováno v:
Chemischer Informationsdienst. 5
Carboxymethylidentrikobaltnonacarbonyl (Ia) sowie seine Ester wie (Ib) bilden in konz. Schwefelsaure ein Acylium-Ion, das als Hexafluorophosphat (II) isolierbar ist.