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Autor:
Ivan V. Stankevich, E. N. Shaposhnikova, Anatolii L. Chistyakov, E. A. Avetisyan, C. P. Solodovnikov, N. N. Bubnov, Boris Tumanskii, S. R. Sterlin
Publikováno v:
Russian Chemical Bulletin. 46:1851-1854
The kinetics of hydrogen abstraction from hydrocarbons by the air-stable perfluoroacetyldiisopropylmethyl radical was studied by ESR, and a reaction mechanism was proposed. The degree of delocalization of the unpaired electron in the model C(5)F3−C