Zobrazeno 1 - 6
of 6
pro vyhledávání: '"C. M. Peach"'
Publikováno v:
J. Chem. Soc., Perkin Trans. 1. :916-922
Buffered acetolysis of the title compound (5) gave the corresponding 17aβ-yl acetate (6), along with olefinic products, but unbuffered acetolysis additionally gave D-homo-5α,13α-androstan-17aα-yl acetate (10), with inversion at C-13. The inversio
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bc2ee9f2ec51e8e90583b8c962685dfc
https://doi.org/10.1039/p19750000916
https://doi.org/10.1039/p19750000916
Autor:
V. Petrow, A. P. Leftwick, Derek Burn, C. M. Peach, Bernard Ellis, Williamson David M, A. K. Hiscock, J. W. Ducker
Publikováno v:
J. Chem. Soc.. :4242-4248
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1a63a0beeeba727217d36d4a52b992f3
https://doi.org/10.1039/jr9630004242
https://doi.org/10.1039/jr9630004242
Publikováno v:
Chemischer Informationsdienst. Organische Chemie. 1
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cccc50910208e43329e05c11b7f6198b
https://doi.org/10.1002/chin.197036408
https://doi.org/10.1002/chin.197036408
Publikováno v:
Chemischer Informationsdienst. 4
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2c3cd91569cceed081501646f0b86221
https://doi.org/10.1002/chin.197334130
https://doi.org/10.1002/chin.197334130
Publikováno v:
J. Chem. Soc., Chem. Commun.. :341-341
Acetolysis of D-homo-5α-androstan-17aβ-yl tosylate (I) gave the 17aβ-yl acetate (II) accompanied by D-homo-5α,13α-androstan-17aα-yl acetate (III), resulting from inversion of configuration at the quaternary centre adjacent to the reaction site.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ccaaa7fa8d093b195f4a097ff28fce06
https://doi.org/10.1039/c39730000341
https://doi.org/10.1039/c39730000341
Publikováno v:
Journal of the Chemical Society C: Organic. :1454
D-Homo-5α-androstan-17a-one, -17-one, and -16-one, and the corresponding epimeric pairs of alcohols and acetates have been prepared. These are valuable reference compounds quasi-enantiomeric to derivatives monosubstituted in ring A. N.m.r. data are
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::770ab9052e76364a7d6ce36eb2981672
https://doi.org/10.1039/j39700001454
https://doi.org/10.1039/j39700001454