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Akademický článek
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Autor:
C. Jongsma, F.M. Bickelhaupt
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 92:1143-1151
The reaction of 2-bromobenzophenone (1) with methyl, ethyl, and phenyl Grignard reagents was found to involve substantial substitution of bromine by the organic group of the Grignard reagent It is shown that substitution occurs by intramolecular nucl
Autor:
A C, Jongsma
Publikováno v:
Nederlands tijdschrift voor tandheelkunde. 118(7-8)
A few decades ago, relatively little was known concerning the pre-eruptive spatial development of permanent molars. The material that formed the basis for this study consisted of 114 dry human mandibles of young children and adolescents. Measurements
Publikováno v:
Tetrahedron Letters. 17:481-484
Publikováno v:
Tetrahedron Letters. 16:199-202
Aus der Arsinsaure (I) erhalt man bei der Behandlung mit Thionylhalogeniden die 5,10-Dihalogeno-5,10-dihydro-arsaanthracene (II), die mit Methanol zu den Methoxy- Verbindungen (III) austauschen.
Publikováno v:
Tetrahedron. 31:2931-2935
The synthesis of 10-methyl-9-phosphaanthracene (1b) is described. Its stability is found to be intermediate between that of the unsubstituted parent compound (1a) and of the 10-phenyl derivative (1c). The electronic structure of this new phosphaaroma
Publikováno v:
Tetrahedron. 32:121-124
1,4-Migration of a phenyl group has been observed when 9-phenyl-10-t-butyl-9,10-dihydro-9-phospha-anthracene 7 was subjected to pyrolysis at 500° or to electron-impact. The reaction is proposed to occur via 1-phosphabicyclo[2.2.1]heptyl-type species
Autor:
F.M. Bickelhaupt, P. de Koe, R.J.M. Weustink, Hans Vermeer, R. Lourens, N.R. Mast, G. L. van Mourik, C. Jongsma
Publikováno v:
Tetrahedron. 32:1921-1930
In the diphenylmethane series, the synthesis of 2,2′ - diiododiphenylmethane ( 4g ) and the improved synthesis of 2,2′ - dibromodiphenylmethane ( 4e ) are reported. The triphenylmethane derivatives, 2-bromo-, 2-iodo-, 2,2′-dichloro-, 2,2′-dib
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 96:265-270
10-Aryl-9-arsaanthracenes (3b,c,d) were conveniently synthesized by flash vacuum pyrolysis at ∼ 500° of 10-mono- and di-substituted 9-aryl-9,10-dihydro-9-arsaanthracenes (11a-f). The yield of 10-aryl-9-arsaanthracenes is found to depend upon the s
Publikováno v:
Tetrahedron. 33:205-209