Zobrazeno 1 - 10
of 246
pro vyhledávání: '"C. Bradley Moore"'
Autor:
Karl-Ludwig Kompa, Jake S. Yeston, C. Bradley Moore, Detlev Proch, Marcus Motzkus, Thomas Witte, Werner Fuß, Lars Windhorn
Publikováno v:
The Journal of Chemical Physics. 119:641-645
Gaseous diazomethane (CH2N2) has been irradiated with femtosecond laser pulses tuned to the CNN asymmetric stretch at 2100 cm−1 in the mid-infrared. Laser-induced fluorescence detection of 1CH2 [537 nm, b1B1(0 16 0)←a1A1(0 0 0)] confirms infrared
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::424113e2ef3f989d8b7400ac89844e19
https://doi.org/10.1063/1.1587696
https://doi.org/10.1063/1.1587696
Publikováno v:
The Journal of Chemical Physics. 118:4452-4455
H or D atom velocities are reported for dissociation from several vibrational levels in the lowest 2500 cm−1 of the A 2A″ state of two vinyl radical isotopomers, C2H3 and CD2CH. Energies are inferred for the acetylene product and compared with bo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d378e9df6e136dc3080bb1ba1f79acbb
https://doi.org/10.1063/1.1542878
https://doi.org/10.1063/1.1542878
Publikováno v:
The Journal of Chemical Physics. 115:10738-10744
The spectra of the X2A′-A2A″ electronic transition of jet-cooled vinyl radical, C2H3, and its partially deuterated isotopomer, CD2CH, have been obtained via action spectroscopy. The appearance of the H or D fragment was monitored via 1+1′ reson
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cc3c6f0060e3ce9176ff50f7f294715f
https://doi.org/10.1063/1.1416495
https://doi.org/10.1063/1.1416495
Publikováno v:
Organometallics. 19:3442-3446
The photochemistry of Tp*Rh(CO)2 (1; Tp* = hydridotris(3,5-dimethylpyrazolyl)borate) in liquid xenon solution at −50 °C has been examined by flash IR kinetic spectroscopy. IR spectra of the solution taken 2 μs after 308 nm photolysis exhibit two
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ad250555b3562010cec34a8395b1130c
https://doi.org/10.1021/om000238w
https://doi.org/10.1021/om000238w
Autor:
Richard G. Shu, Hakhyun Nam, Harry P. Beal, Horst Clauberg, Jason C. Crane, Ilia J. Kalinovski, C. Bradley Moore
Publikováno v:
The Journal of Physical Chemistry A. 102:9433-9444
Dispersed fluorescence (DF) and stimulated emission pumping (SEP) spectra of DFCO from 9000 to 20 000 cm -1 on S0 are reported. Groups of features in the 2 1 5 1 6 2 DF spectrum are assigned as strongly coupled members of 266 [O2(CO stretch) T 2O6(ou
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::73455342c41a7fab1980a55e3c05394f
https://doi.org/10.1021/jp981917b
https://doi.org/10.1021/jp981917b
Publikováno v:
The Journal of Chemical Physics. 108:8944-8949
The extent of K-mixing in the dissociation of ketene on its S0 potential energy surface has been investigated. Using a two-step photodissociation scheme for ketene and laser-induced fluorescence (LIF) to detect the CH2 radical, photofragment excitati
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::629522cd5ebdb1a937d491a7377a180e
https://doi.org/10.1063/1.476339
https://doi.org/10.1063/1.476339
Publikováno v:
The Journal of Physical Chemistry A. 101:6568-6576
The tightening of the transition state as energy increases above the dissociation threshold is studied for the dissociation of singlet ketene. Rate constants and quantum yields have been determined...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6919ac5d0c2ad26ca9c5b79d6f2b0d76
https://doi.org/10.1021/jp9707652
https://doi.org/10.1021/jp9707652
Publikováno v:
Berichte der Bunsengesellschaft für physikalische Chemie. 101:465-468
The effect of K-conservation on the photodissociation of ketene has been investigated. Rate constants and photofragment excitation (PHOFEX) spectra have been calculated using phase space theory (PST) in a helicity basis. While the effect of K-conserv
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6cebda207d1e68a68a797a6667cef1ca
https://doi.org/10.1002/bbpc.19971010319
https://doi.org/10.1002/bbpc.19971010319
Publikováno v:
The Journal of Physical Chemistry A. 101:732-739
The rotational energy release in the dissociation of ketene along its singlet potential energy surface is observed and compared with various statistical and dynamical theories. Rotational distributions for CO(X 1Σ+)(v=1) are measured from the thresh
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::80afaf34ee42989741a87741d9cb2bc2
https://doi.org/10.1021/jp962131l
https://doi.org/10.1021/jp962131l
Publikováno v:
Journal of Molecular Spectroscopy. 177:285-293
The infrared spectra of the ν 2 + ν 3 and ν 2 + ν 4 bands of ketene, from 3526 to 3538 cm −1 and from 3257 to 3277 cm −1 , respectively, have been obtained using an IR–UV double resonance photolysis scheme. A tunable IR laser pulse is follo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b8c490889e1fd163e76522d8867e0b0d
https://doi.org/10.1006/jmsp.1996.0142
https://doi.org/10.1006/jmsp.1996.0142