Switching on thermal and light-induced spin crossover by desolvation of [Fe(3-bpp)2](XO4)2·solvent (X = Cl, Re) compounds

Autor: Rachid Delimi, Farouk Benaceur, Shin-ichi Ohkoshi, Cédric Desplanches, Abdelhak Djemel, Guillaume Chastanet, Kunal Kumar, Olaf Stefańczyk

Publikováno v: Inorganic Chemistry Frontiers
Inorganic Chemistry Frontiers, Royal Society of Chemistry, 2021, 8 (13), pp.3210-3221. ⟨10.1039/d1qi00446h⟩

International audience; Thermal desolvation is a very attractive method for the post-synthetic modification of the physicochemical properties of switchable materials. In this field of research, special attention has been paid to the possibility of mo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e22f3b492fa582156ef5d72255fc1a20
http://hdl.handle.net/20.500.12278/109314

Light-Induced Excited Spin-State Trapping: A Methodological Approach

Autor: Guillaume Chastanet, Mathieu Marchivie, Mathieu Gonidec, Philippe Guionneau, Corine Mathonière, Patrick Rosa, Cédric Desplanches

Publikováno v: Comprehensive Coordination Chemistry III ISBN: 9780081026892
Comprehensive coordination chemistry III
Edwin C. Constable; Gerard Parkin; Lawrence Que; Catherine E. Housecroft. Comprehensive coordination chemistry III, Elsevier, pp.198-216, 2021, 978-0-08-102689-2. ⟨10.1016/B978-0-12-409547-2.14646-3⟩
Reference Module in Chemistry, Molecular Sciences and Chemical Engineering
Jan Reedijk. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, Elsevier, pp.1-19, 2019, 978-0-409547-2. ⟨10.1016/B978-0-12-409547-2.14646-3⟩

International audience; Light-Induced spin state switching has been widely studied over the last 40 years, exploring the different time and size scales. This exploration was performed by using a wide range of techniques which are still growing in res

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ce3ca6da50316d87e0e06223f039de3b
https://doi.org/10.1016/b978-0-12-409547-2.14646-3

Switchable Heteroleptic Mononuclear Iron(II) Complexes as Versatile Molecular Building Block

Autor: Chérif Baldé, Nicolas Paradis, Cédric Desplanches, Guillaume Chastanet

Publikováno v: European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2018, 2018 (19), pp.2004-2010. ⟨10.1002/ejic.201800053⟩

International audience; A series of photoswitchable precursors based on [Fe(NCX)2L(L′)2], where X = S or Se, L is a bidentate ligand (phenanthroline or bipyrimidine), and L′ a monodentate ligand such as a pyridine or picoline derivative, were syn

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c9aa7efe6020ee444d15a286efbbc7d1
https://doi.org/10.1002/ejic.201800053

Electronic and Structural Dynamics During the Switching of the Photomagnetic Complex [Fe(L 222 N 5 )(CN) 2 ]

Autor: X. Dong, Guillaume Chastanet, Marco Cammarata, James M. Glownia, Cédric Desplanches, Maciej Lorenc, Serhane Zerdane, Eric Collet, Samir F. Matar, Henrick T. Lemke, Hong Feng Wang, Matthieu Chollet

Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, 2018, 24 (20), pp.5064-5069. ⟨10.1002/chem.201704746⟩
Chemistry-A European Journal, 2018, 24 (20), pp.5064-5069. ⟨10.1002/chem.201704746⟩

International audience; The [Fe(L N )(CN) ] compound, where L N refers to the macrocyclic Schiff-base ligand, 2,13-dimethyl-3,6,9,-12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,- 16-pentaene, is a photomagnetic Fe based coordination compound, w

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6fd81eef03fe57da387cd8a9ab5bbf1f
https://doi.org/10.1002/chem.201704746

Supramolecular iron metallocubanes exhibiting site-selective thermal and light-induced spin-crossover

Autor: Rafal Kulmaczewski, Malcolm A. Halcrow, Juliusz A. Wolny, Tim Hochdörffer, Izar Capel Berdiell, Namrah Shahid, Cédric Desplanches, Volker Schünemann, Oscar Cespedes, Stuart L. Warriner, Guillaume Chastanet

Publikováno v: Journal of the American Chemical Society
Journal of the American Chemical Society, American Chemical Society, 2019, 141 (47), pp.18759-18770. ⟨10.1021/jacs.9b08862⟩

International audience; Treatment of Fe[BF4]2·6H2O with 4,6-di(pyrazol-1-yl)-1H-pyrimid-2-one (HL1) or 4,6-di(4-methylpyrazol-1-yl)-1H-pyrimid-2-one (HL2) affords solvated crystals of [{FeIII(OH2)6}⊂FeII8(μ-L)12][BF4]7 (1, HL = HL1; 2, HL = HL2).

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ae02b2fa522a683c7ba79fbf438236da
https://hal.archives-ouvertes.fr/hal-02383213