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Publikováno v:
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 57:705-716
A novel ion cell has been constructed for the purpose of studying rotationally inelastic collisions involving truly thermal molecular ions at low temperatures. With this ion cell, time-resolved double resonance (pump-probe) spectroscopic experiments
Publikováno v:
The Astrophysical Journal. 521:255-260
Methyl formate (HCOOCH3), a threefold internal rotor, is a well-known interstellar molecule located in hot cores of giant molecular clouds. Over a decade ago, we published separate analyses of the rotational-torsional spectra of methyl formate in its
Autor:
K. V. L. N. Sastry, Frank C. De Lucia, L. C. Oesterling, Eric Herbst, Fiona L. Bettens, Sieghard Albert
Publikováno v:
The Astrophysical Journal. 510:789-794
Methyl mercaptan (CH3SH), a threefold internal rotor and the sulfur analog of methanol, has been detected in the interstellar medium, although little is known about its chemistry or about the physical conditions most favorable for its synthesis. Unti
Publikováno v:
Physical Review Letters. 75:2940-2943
A novel apparatus has been developed to produce large quantities of thermal molecular ions at temperatures well below the freezing points of their precursor neutrals. This apparatus has been used to study the pressure broadening of the $J\phantom{\ru
Publikováno v:
Journal of Molecular Spectroscopy. 172:469-484
The rotational-torsional spectrum of DCOOCH3, the symmetric, singly deuterated isotopomer of methyl formate, has been extended into the millimeter-wave and submillimeter-wave regions of the electromagnetic spectrum. A total of 885 lines belonging to
Publikováno v:
Journal of Molecular Spectroscopy. 167:365-374
Torsional splittings in both the 2ν 9 , and ν 5 vibrational states have been resolved and observed in the millimeter/submillimeter spectrum of HNO 3 . The former splitting is due to the torsional motion of H around the NO bond in the ν 9 mode, whe
Publikováno v:
European Respiratory Journal. 7:1221-1226
Abnormal collagen metabolism is a hallmark of diffuse lung disease. Biochemical parameters which are correlated with collagen synthesis and degradation may be helpful to monitor fibrosis. In this study, we compared the sensitivity and specificity of
Publikováno v:
British Journal of Cancer
The interval required for haematological reconstitution following myelosuppressive chemotherapy can be reduced by the infusion of autologous peripheral blood progenitor cells (PBPCs). When carboplatin (C) and paclitaxel (P) are followed by granulocyt
Publikováno v:
Gut. 63:A235.1-A235
Introduction Community based specialist clinics improve patient experience and access to healthcare whilst improving GP-Specialist communication. 1 Commissioning dictates that future management of chronic gastro-intestinal conditions needs to involve