Conformations and Low-Frequency Intramolecular Motions of 1-Butanol, 1-Butanethiol, Iso-butanol, and Iso-butanethiol Investigated by Fourier Transform Microwave Spectroscopy Combined with Quantum Chemical Calculations

Autor: Yoshiyuki Kawashima, Taigo Uzuyama, Yugo Tanaka, Eizi Hirota

Publikováno v: The Journal of Physical Chemistry A. 125:1166-1183

The rotational spectra of 1-butanol (1-BuOH), 1-butanethiol (1-BuSH), 2-methyl-1-propanol (iso-BuOH), and 2-methyl-1-propanethiol (iso-BuSH) were measured by Fourier transform microwave spectroscopy in the frequency region from 3.7 up to 25 GHz. The

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::647114a43c0b085e22b4affebe7a35d5
https://doi.org/10.1021/acs.jpca.0c09687

Elucidation of the Structure of a Thiol Functionalized Cu-tmpa Complex Anchored to Gold via a Self-Assembled Monolayer

Autor: Longfei Wu, Daan den Boer, Dennis G. H. Hetterscheid, Nicole W. G. Smits, Jan P. Hofmann

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, 58(19), 13007-13019
'Inorganic Chemistry ', vol: 58, pages: 13007-13019 (2019)
Inorganic Chemistry, 58(19), 13007-13019. American Chemical Society

The structure of the copper complex of the 6-((1-butanethiol)oxy)-tris(2-pyridylmethyl)amine ligand (Cu-tmpa-O(CH2)4SH) anchored to a gold surface has been investigated. To enable covalent attachment of the complex to the gold surface, a heteromolecu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ce4b11913a55a3fa88f81c8e771232c3
http://europepmc.org/articles/PMC6784813

2-Butanthiol

Autor: Hartwig, Andrea, MAK Commission

The German Commission for the Investigation of Health Hazards of Chemical Compounds in the Work Area has evaluated data for 2-butanethiol [513-53-1] considering all toxicological end points. Data from a 90-day inhalation study with rats show that the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5b963d62d65231b68bdb7d714f9d4a72

Thioetherification of isoprene and butanethiol on transition metal phosphides

Autor: Tianyu Ren, Jixiang Chen, Yang Chu, Mingfeng Li

Publikováno v: Journal of Energy Chemistry. 27:930-939

Thioetherification between mercaptan and diolefin is an efficient process to remove mercaptans in FCC gasoline at mild condition, during which the selective hydrogenation of diolefin to monoolefin is also expected. Here, SiO2 supported transition met

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::efdb7aef89a2d6641038776f35c1d5dd
https://doi.org/10.1016/j.jechem.2017.07.017

Fundamental research on the influence of mercaptan and thioether structure on the solvent extraction of fluid catalytic cracking naphtha

Autor: Chunming Xu, Xuhui Gao, Zhang Yuhao, Liang Zhao, Mengmeng Liu, Mengqi Liu, Xiangqi Liu, Jinsen Gao

Publikováno v: Separation and Purification Technology. 270:118747

The thioether and mercaptan components (over 50–100 mg/kg) of fluid catalytic cracking (FCC) naphtha must be removed to satisfy the rigorous sulfur content standard of the vehicle gasoline. Owing to the difference between the structures of thioethe

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8a67abfafbc5832da3bc255c04fd4fd3
https://doi.org/10.1016/j.seppur.2021.118747