Výsledky vyhledávání

Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag6H4(dppm)4(OAc)2] and [Cu3H(dppm)3(OAc)2]

Autor: Cook, AW, Nguyen, T-AD, Buratto, WR, Wu, G, Hayton, TW

Publikováno v: Inorganic chemistry, vol 55, iss 23
Cook, AW; Nguyen, T-AD; Buratto, WR; Wu, G; & Hayton, TW. (2016). Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag6H4(dppm)(4)(OAc)(2)] and [Cu3H(dppm)(3)(OAc)(2)]. INORGANIC CHEMISTRY, 55(23), 12435-12440. doi: 10.1021/acs.inorgchem.6b02385. UC Santa Barbara: Retrieved from: http://www.escholarship.org/uc/item/9bm0100j

The group 11 hydride clusters [Ag6H4(dppm)4(OAc)2] (1) and [Cu3H(dppm)3(OAc)2] (2) (dppm = 1,1-bis(diphenylphosphino)methane) were synthesized in moderate yields from the reaction of M(OAc) (M = Ag, Cu) with Ph2SiH2, in the presence of dppm. Complex

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A Cu25 Nanocluster with Partial Cu(0) Character

Autor: Nguyen, TAD, Jones, ZR, Goldsmith, BR, Buratto, WR, Wu, G, Scott, SL, Hayton, TW

Publikováno v: Nguyen, TAD; Jones, ZR; Goldsmith, BR; Buratto, WR; Wu, G; Scott, SL; et al.(2015). A Cu25 Nanocluster with Partial Cu(0) Character. Journal of the American Chemical Society, 137(41), 13319-13324. doi: 10.1021/jacs.5b07574. UC Santa Barbara: Retrieved from: http://www.escholarship.org/uc/item/6qt9b1pk

© 2015 American Chemical Society. Atomically precise copper nanoclusters (NCs) are of immense interest for a variety of applications, but have remained elusive. Herein, we report the isolation of a copper NC, [Cu25H22(PPh3)12]Cl (1), from the reacti

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Akademický článek

Cleavage of cluster iron-sulfide bonds in cyclophane-coordinated Fe n S m complexes.

Autor: Buratto WR; Department of Chemistry, Center for Catalysis, University of Florida, Gainesville, FL 32611-7200, USA. murray@chem.ufl.edu., Ferreira RB, Catalano VJ, García-Serres R, Murray LJ

Publikováno v: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2021 Jan 21; Vol. 50 (3), pp. 816-821. Date of Electronic Publication: 2021 Jan 04.

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Akademický článek

Activation of Dinitrogen by Polynuclear Metal Complexes.

Autor: Singh D; Center for Catalysis, and Florida Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, United States., Buratto WR; Center for Catalysis, and Florida Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, United States., Torres JF; Center for Catalysis, and Florida Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, United States., Murray LJ; Center for Catalysis, and Florida Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, United States.

Publikováno v: Chemical reviews [Chem Rev] 2020 Jun 24; Vol. 120 (12), pp. 5517-5581. Date of Electronic Publication: 2020 May 04.

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Akademický článek

Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag 6 H 4 (dppm) 4 (OAc) 2 ] and [Cu 3 H(dppm) 3 (OAc) 2 ].

Autor: Cook AW; Department of Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States., Nguyen TD; Department of Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States., Buratto WR; Department of Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States., Wu G; Department of Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States., Hayton TW; Department of Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.

Publikováno v: Inorganic chemistry [Inorg Chem] 2016 Dec 05; Vol. 55 (23), pp. 12435-12440. Date of Electronic Publication: 2016 Nov 21.

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Akademický článek

A Cu25 Nanocluster with Partial Cu(0) Character.

Autor: Nguyen TA; Department of Chemistry & Biochemistry, and ‡Department of Chemical Engineering, University of California , Santa Barbara, California 93106, United States., Jones ZR; Department of Chemistry & Biochemistry, and ‡Department of Chemical Engineering, University of California , Santa Barbara, California 93106, United States., Goldsmith BR; Department of Chemistry & Biochemistry, and ‡Department of Chemical Engineering, University of California , Santa Barbara, California 93106, United States., Buratto WR; Department of Chemistry & Biochemistry, and ‡Department of Chemical Engineering, University of California , Santa Barbara, California 93106, United States., Wu G; Department of Chemistry & Biochemistry, and ‡Department of Chemical Engineering, University of California , Santa Barbara, California 93106, United States., Scott SL; Department of Chemistry & Biochemistry, and ‡Department of Chemical Engineering, University of California , Santa Barbara, California 93106, United States., Hayton TW; Department of Chemistry & Biochemistry, and ‡Department of Chemical Engineering, University of California , Santa Barbara, California 93106, United States.

Publikováno v: Journal of the American Chemical Society [J Am Chem Soc] 2015 Oct 21; Vol. 137 (41), pp. 13319-24. Date of Electronic Publication: 2015 Oct 13.

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Akademický článek

Dinitrogen cleavage and hydrogenation to ammonia with a uranium complex.

Autor: Xin, Xiaoqing^1,2 (AUTHOR), Douair, Iskander³ (AUTHOR), Zhao, Yue¹ (AUTHOR), Wang, Shuao⁴ (AUTHOR), Maron, Laurent³ (AUTHOR) laurent.maron@irsamc.ups-tlse.fr, Zhu, Congqing¹ (AUTHOR) zcq@nju.edu.cn

Publikováno v: National Science Review. Feb2023, Vol. 10 Issue 2, p1-9. 9p.

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