Stepwise Collapse of a Giant Pore Metal–Organic Framework

Autor: Sapnik, AF, Johnstone, DN, Collins, SM, Divitini, G, Bumstead, AM, Ashling, CW, Chater, PA, Keeble, DS, Johnson, T, Keen, DA, Bennett, TD

Defect engineering is a powerful tool that can be used to tailor the properties of metal–organic frameworks (MOFs). Here, we incorporate defects through ball milling to systematically vary the porosity of the giant pore MOF, MIL-100 (Fe). We show t

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=core_ac_uk__::25ace4cd3580163653706e3a51e4d13f
https://eprints.whiterose.ac.uk/172511/7/d1dt00881a.pdf

Formation of new crystalline qtz-[Zn(mIm)2] polymorph from amorphous ZIF-8.

Autor: Thorne MF; Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk., Castillo-Blas C; Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk., McHugh LN; Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk., Bumstead AM; Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk., Robertson G; Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk., Sapnik AF; Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk., Coates CS; Yusuf Hamied Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK., Sayed FN; Yusuf Hamied Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK., Grey CP; Yusuf Hamied Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK., Keen DA; ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Didcot, OX11 0QX, UK., Etter M; Deutsches Elektronen Synchrotron, FS-PETRA-D, P02.1, Notkestr. 85, 22607, Hamburg, Germany., da Silva I; ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Didcot, OX11 0QX, UK., Užarević K; Ruđer Bošković Institute, Bijenička Cesta 54, Zagreb, HR-10000, Croatia., Bennett TD; Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk.

Publikováno v: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2022 Oct 25; Vol. 58 (85), pp. 11949-11952. Date of Electronic Publication: 2022 Oct 25.

Multivariate analysis of disorder in metal-organic frameworks.

Autor: Sapnik AF; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK., Bechis I; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London, W12 0BZ, UK., Bumstead AM; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK., Johnson T; Johnson Matthey Technology Centre, Blount's Court, Sonning Common, Reading, RG4 9NH, UK., Chater PA; Diamond Light Source Ltd, Diamond House, Harwell Campus, Didcot, Oxfordshire, OX11 0DE, UK., Keen DA; ISIS Neutron and Muon Facility, Rutherford Appleton Laboratory, Harwell Campus, Didcot, Oxfordshire, OX11 0QX, UK., Jelfs KE; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London, W12 0BZ, UK., Bennett TD; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk.

Publikováno v: Nature communications [Nat Commun] 2022 Apr 21; Vol. 13 (1), pp. 2173. Date of Electronic Publication: 2022 Apr 21.

Plasticity of Metal-Organic Framework Glasses.

Autor: Widmer RN; Empa-Swiss Federal Laboratories for Materials Science and Technology, Feuerwerkerstrasse 39, 3602 Thun, Switzerland., Bumstead AM; Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, CB3 0FS, U.K., Jain M; Empa-Swiss Federal Laboratories for Materials Science and Technology, Feuerwerkerstrasse 39, 3602 Thun, Switzerland., Bennett TD; Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, CB3 0FS, U.K., Michler J; Empa-Swiss Federal Laboratories for Materials Science and Technology, Feuerwerkerstrasse 39, 3602 Thun, Switzerland.

Publikováno v: Journal of the American Chemical Society [J Am Chem Soc] 2021 Dec 15; Vol. 143 (49), pp. 20717-20724. Date of Electronic Publication: 2021 Dec 02.

Stepwise collapse of a giant pore metal-organic framework.

Autor: Sapnik AF; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk., Johnstone DN, Collins SM, Divitini G, Bumstead AM, Ashling CW, Chater PA, Keeble DS, Johnson T, Keen DA, Bennett TD

Publikováno v: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2021 Apr 14; Vol. 50 (14), pp. 5011-5022. Date of Electronic Publication: 2021 Mar 26.