Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Bryony L. Elbert"'
Publikováno v:
Organic Letters
Resolvins D3 and E1 are important signaling molecules in the resolution of inflammation. Here, we report a convergent and flexible strategy to prepare these natural products using Hiyama–Denmark coupling of five- and six-membered cyclic alkenylsilo
Autor:
Bryony L. Elbert, Christian J. Kuper, Felix Urbitsch, Damien Cornut, Edward A. Anderson, Haraldur G. Gudmundsson
Publikováno v:
The Journal of organic chemistry. 84(22)
Cyclic dimethylalkenylsiloxanes, useful motifs for (Z)-selective Hiyama cross-coupling, are accessed from alkynyl benzyldimethylsilanes featuring adjacent allylic or homoallylic oxygen substituents by semihydrogenation/debenzylation/cyclization. Whil
Autor:
Timothy W. Gorman, Benedicte Lallemand, Malcolm MacCoss, Michael C. Willis, Christopher J. Schofield, José L. Castro, Alistair J. M. Farley, Darren J. Dixon, Martin D. Smith, Bryony L. Elbert, Tarn C. Johnson, Jakub Flasz, Christophe Genicot, Robert S. Paton, Patrick Pasau
Publikováno v:
Chemical Science. 9(3)
Sulfones feature prominently in biologically active molecules and are key functional groups for organic synthesis. We report a mild, photoredox-catalyzed reaction for sulfonylation of aniline derivatives with sulfinate salts, and demonstrate the util
Autor:
Jack A. O'Hanlon, Diane S. W. Lim, Bryony L. Elbert, Edward A. Anderson, Haraldur G. Gudmundsson
Publikováno v:
ChemInform. 46
The general route to cyclic alkenylsiloxanes, based on the Lindlar hydrogenation of alkynylsilanes, solves a long-standing selectivity issue in alkynylsilane reduction chemistry.
Autor:
Edward A. Anderson, Haraldur G. Gudmundsson, Jack A. O'Hanlon, Diane S. W. Lim, Bryony L. Elbert
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
Cyclic alkenylsiloxanes were synthesized by semihydrogenation of alkynylsilanes - a reaction previously plagued by poor stereoselectivity. The silanes, which can be synthesized on multigram scale, undergo Hiyama-Denmark coupling to give (Z)-alkenyl p
Autor:
Elizabeth C. Frye, David G. Hulcoop, Cornelius J. O'Connor, David G. Twigg, David R. Spring, Luca Laraia, Ashok R. Venkitaraman, Bryony L. Elbert
Publikováno v:
ChemInform. 43
The title Hiyama reaction is performed with allylic chlorides and bromides, and benzylic chlorides, bromides, tosylates and mesylates.