Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Bryan J. Ward"'
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
sp3C−F Bonds of fluoroalkanes (7 examples; 1°, 2° and 3°) undergo addition to a low‐valent Mg−Mg species generating reactive organomagnesium reagents. Further reactions with a series of electrophiles results in a net C−F to C−B, C−Si,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::95c2043af171fbf26c7797a76e20b4ad
https://pubmed.ncbi.nlm.nih.gov/30207410
https://pubmed.ncbi.nlm.nih.gov/30207410
Publikováno v:
Chemical Science
Through a combined experimental and computational (DFT) approach, the reaction mechanism of the addition of fluoroarenes to Mg–Mg bonds has been determined as a concerted SNAr-like pathway in which one Mg centre acts as a nucleophile and the other
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b9c0858d0b5957de64990f0dcfdc4a72
Autor:
Andrew J. P. White, Laurence R. Doyle, Thomas J. Herrington, Patricia A. Hunt, Bryan J. Ward, Joe McDermott, Andrew E. Ashley
Publikováno v:
Chem. Commun.. 50:12753-12756
The thermally robust silylium complex [iPr3Si–PtBu3]+[B(C6F5)4]− (1) activates H2/D2 at 90 °C (PhCl). However, experimental evidence and DFT calculations show no evidence for dissociation into the separated Lewis pair.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c7c52a0058ff8e2fb1436eedfef41daf
https://doi.org/10.1039/c4cc05905k
https://doi.org/10.1039/c4cc05905k
Autor:
Patricia A. Hunt, Bryan J. Ward
A computational investigation of the intermolecular hydrophosphination of styrene and 2-vinylpyridine, catalyzed by the heteroleptic β-diketiminato-stabilized calcium complex [(PhNC(Me)CHC(Me)NPh)CaPPh2], is presented. Alkene insertion does not proc
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::abb7fd32aab2dcc2133e372d8aee6669
http://hdl.handle.net/10044/1/44385
http://hdl.handle.net/10044/1/44385
