Zobrazeno 1 - 10
of 41
pro vyhledávání: '"Bruno M. Vittimberga"'
Publikováno v:
Synthetic Communications. 33:2605-2611
The o-nitrobenzyl group, possessing distinct advantage of being photolabile under mild conditions, was successfully connected to 8-(5,6-epoxynorbornan-2-yl)-1,3-dipropylxanthine (5), a high specific A1 adenosine receptor antagonist. The resulting com
Autor:
Bruno M. Vittimberga, Donald F. Sears
Publikováno v:
Journal of Heterocyclic Chemistry. 38:285-291
The physical and photophysical properties of 6-phenanthridinecarbonitrile (1) have been examined. We previously reported that when 1 is irradiated in aqueous 2-propanol, three products are formed [3]. These include dimethyl-6-phenanthridinylcarbinol
Autor:
Donald F. Sears, Bruno M. Vittimberga
Publikováno v:
Journal of Heterocyclic Chemistry. 37:291-295
When 6-phenanthridinecarbonitrile (3) is irradiated at 2537 A in neutral 9:1 2-propanol/water, three major products are formed. These are dimethyl-(6-phenanthridinyl)methanol (4), phenanthridine (5) and 6,6′-biphenanthridine (6). When benzophenone
Autor:
Bruno M. Vittimberga, Anne L. Rieger
Publikováno v:
Journal of Heterocyclic Chemistry. 37:131-136
When a 1° or 2° alcohol solution of benzophenone and 2,4-pyridinedicarbonitrile (1) is irradiated, the 2,4-dicyanopyridinyl radical (2) is formed immediately. When the irradiation is performed in the cavity of an ESR spectrometer, the spectrum ampl
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 90:137-140
The photochemistry of a variety of dicyanopyridines (2,3-, 2,4-, 2,5-, 2,6-, 3,4- and 3,5-dicyanopyridine) in solution at room temperature was investigated. Pulsed UV (308 nm) laser irradiation in deoxygenated acetonitrile yields the triplet state wi
Publikováno v:
Journal of Heterocyclic Chemistry. 31:903-908
A study on the photochemically induced electron-transfer from primary and secondary aliphatic amines as donors to pyridinedicarbonitriles as the acceptor is reported. A comparison between the substitution posi- tions and the spin density distribution
Publikováno v:
ChemInform. 22
Electron transfer reactions of cyano substituted pyridines and quinolines with thermally generated diphenyl ketyl are reported. When E1/2(-) for the heterocycle is less negative than -2V, electron transfer occurs from the ketyl to the heterocyclic ba
Autor:
Sergio Morrocchi, Bruno M. Vittimberga, T. Caronna, D. Dal Pio Luogo, Rosanna Bernardi, Gabriella Poggi
Publikováno v:
ChemInform. 27
Autor:
Bruno M. Vittimberga, Donald F. Sears
Publikováno v:
ChemInform. 31
Autor:
Bruno M. Vittimberga, Tullio Caronna
Publikováno v:
Journal of Heterocyclic Chemistry. 29:787-790
Total energies of 2-, 3-, 4- and disubstituted pyridines were calculated for the salt and the free base using ab initio molecular orbital calculations at the STO-3G basis set level [2]. In each set, the difference in energy, ΔEH, between the salt an