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Autor:
Isabelle Durand, Trang N. T. Phan, Pierre-Emmanuel Dufils, Bruno Giovanetti, Sylvain R. A. Marque, Didier Gigmes, Yohann Guillaneuf, Denis Bertin, Paul Tordo
Publikováno v:
Macromolecular Chemistry and Physics. 209:220-224
The effect of the penultimate unit on the C-ON bond homolysis rate constant k d was studied for model alkoxyamines. It was shown that the k d for fragments containing penultimate and antepenultimate units were nicely predicted by the tri-parametric r