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Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 163:381-388
A series of mononuclear and binuclear ruthenium(II) heteroleptic complexes as potential sensitizers for DNA photocleavage has been synthesized and characterized. This series based on 1,10-phenanthroline (phen) ligands is of the type [Rux(phen)2x(L)]2
Autor:
Régis Calvayrac, Francine Bruston, Marie-Hélène Baron, Bruno Drahi, Jacques Vergne, Marie-Christine Maurel, Lydie Grajcar
Publikováno v:
Biochemical and Biophysical Research Communications. 263:672-677
In solutions of CuCl2 and adenine copper can be bound to adenine. Two Cu(adenine)(2) complexes [Cu(C(5)H(5)N(5))(2)]2+/Cu(C(5)H(4)N(5))(2)] are in equilibrium with free adenine. Copper-adenine complexes present a catalytic activity (e.g., H(2)O(2) di