Zobrazeno 1 - 5
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pro vyhledávání: '"Bror Johan Wik"'
Autor:
Bror Johan Wik, Mats Tilset
Publikováno v:
Journal of Organometallic Chemistry. 692:3223-3230
The oxidation of the Pt(IV) tetramethyl complex [Ar N CH CH N Ar]PtMe 4 (Ar = 2,6-Me 2 C 6 H 3 ) has been investigated in acetonitrile and dichloromethane. Cyclic voltammetry demonstrates that the irreversible oxidation of [Ar N CH CH N Ar]PtMe 4 occ
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 189:23-32
Reactions between [Cp∗IrCl2]2 and diaryl-substituted diazabutadienes (dab) ArNCR′CR′NAr (R′=H: Ar=4-MeC6H4, 2,6-Me2C6H3, 2,6- i Pr 2 C 6 H 3 ; R′=Me: Ar=4-MeC6H4) proceed straightforwardly to give the dab complexes Cp∗Ir(dab)Cl+C
Publikováno v:
Journal of the American Chemical Society. 128(8)
Protonation of (N-N)PtPh(2) (1; N-N = diimine ArN=CMe-CMe=NAr with Ar = 2,6-Me(2)C(6)H(3) (a), 2,4,6-Me(3)C(6)H(2) (b), 4-Br-2,6-Me(2)C(6)H(2) (c), 3,5-Me(2)C(6)H(3) (d), and 4-CF(3)C(6)H(4) (e)) in the presence of MeCN at ambient temperature generat
Publikováno v:
ChemInform. 36
Rapid equilibria between M(a-hydrocarbon) and M(H)(hydrocarbyl) species is a distinct feature of C-H activation reactions at transition-metal complexes of great structural diversity. In this contribution, we summarize recent work that has been done i
Publikováno v:
Journal of the American Chemical Society. 124(41)
Protonolysis of (diimine)PtMe2 (1) complexes in CD2Cl2 containing CD3CN at -78 degrees C yields (diimine)PtMe2(H)(NCCD3)+ (4), (diimine)PtMe(NCCD3)+ (5), and methane. The relative yields of 5 and methane decrease with increasing concentrations of CD3