Zobrazeno 1 - 10
of 18
pro vyhledávání: '"Brooks J. Hornstein"'
Publikováno v:
Langmuir. 22:9357-9367
Following an introduction to the nanocluster stabilization literature and DLVO (Derjaugin-Landau-Verwey-Overbeek) theory of colloidal stability, the most common steric stabilizer of transition-metal nanoclusters, poly(vinylpyrrolidone) (PVP), has bee
Autor:
Thomas J. Meyer, Laurie A. Gallagher, Brooks J. Hornstein, Scafford A. Serron, Xingu Wen, Jon R. Schoonover, Dana M. Dattelbaum
Publikováno v:
Inorganic Chemistry. 44:2089-2097
Photocurrent measurements have been made on nanocrystalline TiO2 surfaces derivatized by adsorption of a catalyst precursor, [Ru(tpy)(bpy(PO3H2)2)(OH2)]2+, or chromophore, [Ru(bpy)2 (bpy(PO3H2)2)]2+ (tpy is 2,2':6',2' '-terpyridine, bpy is 2,2'-bipyr
Publikováno v:
Chemistry of Materials. 16:139-150
A kinetic method following the development, and then the loss, of catalytic activity is used to monitor the nucleation, growth, and then pyridine or acetonitrile-induced agglomeration (also called aggregation, coagulation, or flocculation) of modern,
Publikováno v:
Inorganic Chemistry. 42:6923-6928
Aqueous solutions of potassium ferrate(VI) cleanly and rapidly oxidize hydroxylamine to nitrous oxide, N-methylhydroxylamine to nitrosomethane, N-phenylhydroxylamine to nitrosobenzene, and O-methylhydroxylamine to methanol and nitrogen. The kinetics
Publikováno v:
Chemistry of Materials. 15:899-909
Previously, we reported the milligram-scale synthesis of tetrabutylammonium- and polyoxoanion (P2W15Nb3O629-)-stabilized Ir(0) nanoclusters. To increase the isolable yield of this nanocluster catalyst material to near 1 g, experiments were carried ou
Publikováno v:
Inorganic Chemistry. 41:1625-1638
It is crucial in metal particle catalysis to know the true number of catalytically active surface sites; without this knowledge it is impossible (i) to know the true turnover frequency (TOF, i.e., the moles of product/(moles of active metal atoms ×
Autor:
Hershel Jude, Dana M. Dattelbaum, Darla Graff Thompson, Luis M. Baraldo, Javier J. Concepcion, Joe D. Thompson, Jonah W. Jurss, Reginaldo C. Rocha, Estelle L. Lebeau, Kristin M. Omberg, Jennifer M. Butler, Brooks J. Hornstein, Joseph L. Templeton, Jon R. Schoonover, Thomas J. Meyer
Publikováno v:
Inorganic chemistry. 51(3)
The first designed molecular catalyst for water oxidation is the "blue dimer", cis,cis-[(bpy) 2(H 2O)Ru IIIORu III(OH 2)(bpy) 2] 4+. Although there is experimental evidence for extensive electronic coupling across the μ-oxo bridge, results of earlie
Publikováno v:
Inorganica Chimica Acta. 225:145-150
The kinetics of the reaction of ferrate, FeO42−, and hydrazines in aqueous media have been investigated and the results are reported. It was found that ferrate rapidly oxidizes hydrazine to molecular nitrogen and monomethylhydrazine to molecular ni
Publikováno v:
Ferrates ISBN: 9780841269613
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ec85276cb4506fbca31b5d4837313615
https://doi.org/10.1021/bk-2008-0985.ch012
https://doi.org/10.1021/bk-2008-0985.ch012
Publikováno v:
Inorganic chemistry. 46(20)
The phosphonated ruthenium complex, [Ru(tpy-PO(3)H(2))(OH(2))(3)](2+) (1) (tpy-PO(3)H(2) = 4'-phosphonato-2,2':6',2' '-terpyridine), was synthesized and attached to glass|ITO or glass|ITO|TiO(2) electrodes. After attachment to the metal oxide surface