Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Brisco L. Harward"'
Publikováno v:
Journal of Organometallic Chemistry. 429:119-134
In situ spectroscopic studies of the iridium chemistry occurring during the catalytic hydrogenation of carbon monoxide employing IrCl(CO)3 and Ir4(CO)12 in an aluminum chloride-sodium chloride (63:37 mole%) melt were performed. Infrared, UV-visible,
Autor:
E. M. Hondrogiannis, A.G. Edwards, Paul A. Flowers, Brisco L. Harward, D. S. Trimble, J.E. Coffield, Gleb Mamantov, Leon N. Klatt, Louis J. Tortorelli
Publikováno v:
ECS Proceedings Volumes. :794-804
Two aspects of chemistry in alkali chloroaluminate melts are discussed. The first topic involves in situ spectroscopic studies of IrCl(CO){sub 3} and Ir{sub 4}(CO){sub 12} during the catalytic hydrogenation of CO in an AlCl{sub 3}-NaCl (63-37 mole %)
Publikováno v:
Analytical Chemistry. 57:1773-1775
Although various spectroelectrochemical methods have been applied to studies in molten salt media, the development of techniques and apparatus to improve the optical sensitivity of such measurements is nonexistent. The corrosive nature, moisture sens