Unraveling the Bonding Complexity of Polyhalogen Anions: High-Pressure Synthesis of Unpredicted Sodium Chlorides Na$_2$Cl$_3$ and Na$_4$Cl$_5$ and Bromide Na$_4$Br$_5$

Autor: Yin, Yuqing, Aslandukova, Alena, Jena, Nityasagar, Trybel, Florian, Abrikosov, Igor A., Winkler, Bjoern, Khandarkhaeva, Saiana, Fedotenko, Timofey, Bykova, Elena, Laniel, Dominique, Bykov, Maxim, Aslandukov, Andrii, Akbar, Fariia Iasmin, Glazyrin, Konstantin, Garbarino, Gaston, Giacobbe, Carlotta, Bright, Eleanor L., Jia, Zhitai, Dubrovinsky, Leonid, Dubrovinskaia, Natalia

Publikováno v: JACS Au 3(6), 1634 – 1641 (2023). doi:10.1021/jacsau.3c00090

JACS Au 3(6), 1634 – 1641 (2023). doi:10.1021/jacsau.3c00090
The field of polyhalogen chemistry, specifically polyhalogen anions (polyhalides), is rapidly evolving. Here, we present the synthesis of three sodium halides with unpredicted chemic

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Unraveling the Bonding Complexity of Polyhalogen Anions: High-Pressure Synthesis of Unpredicted Sodium Chlorides Na 2 Cl 3 and Na 4 Cl 5 and Bromide Na 4 Br 5 .

Autor: Yin Y; Material Physics and Technology at Extreme Conditions, Laboratory of Crystallography, University of Bayreuth, Bayreuth 95440, Germany.; State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China., Aslandukova A; Bayerisches Geoinstitut, University of Bayreuth, Bayreuth 95440, Germany., Jena N; Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping SE-581 83, Sweden., Trybel F; Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping SE-581 83, Sweden., Abrikosov IA; Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping SE-581 83, Sweden., Winkler B; Institute für Geowissenschaften, Frankfurt University, Altenhöferallee 1, Frankfurt am Main DE-60438, Germany., Khandarkhaeva S; Bayerisches Geoinstitut, University of Bayreuth, Bayreuth 95440, Germany., Fedotenko T; Photon Science, Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, 22607 Hamburg, Germany., Bykova E; Bayerisches Geoinstitut, University of Bayreuth, Bayreuth 95440, Germany.; Earth and Planets Laboratory, Carnegie Institution for Science, 5241 Broad Branch Road, NW, Washington, District of Columbia 20015, United States., Laniel D; Centre for Science at Extreme Conditions and School of Physics and Astronomy, University of Edinburgh, Edinburgh EH9 3FD, U.K., Bykov M; Institute of Inorganic Chemistry, University of Cologne, Greinstrasse 6, Cologne 50939, Germany., Aslandukov A; Material Physics and Technology at Extreme Conditions, Laboratory of Crystallography, University of Bayreuth, Bayreuth 95440, Germany.; Bayerisches Geoinstitut, University of Bayreuth, Bayreuth 95440, Germany., Akbar FI; Material Physics and Technology at Extreme Conditions, Laboratory of Crystallography, University of Bayreuth, Bayreuth 95440, Germany.; Bayerisches Geoinstitut, University of Bayreuth, Bayreuth 95440, Germany., Glazyrin K; Photon Science, Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, 22607 Hamburg, Germany., Garbarino G; European Synchrotron Radiation Facility, B.P.220, Grenoble Cedex F-38043, France., Giacobbe C; European Synchrotron Radiation Facility, B.P.220, Grenoble Cedex F-38043, France., Bright EL; European Synchrotron Radiation Facility, B.P.220, Grenoble Cedex F-38043, France., Jia Z; State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China., Dubrovinsky L; Bayerisches Geoinstitut, University of Bayreuth, Bayreuth 95440, Germany., Dubrovinskaia N; Material Physics and Technology at Extreme Conditions, Laboratory of Crystallography, University of Bayreuth, Bayreuth 95440, Germany.; Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping SE-581 83, Sweden.

Publikováno v: JACS Au [JACS Au] 2023 Jun 05; Vol. 3 (6), pp. 1634-1641. Date of Electronic Publication: 2023 Jun 05 (Print Publication: 2023).