Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Brian K. MacIver"'
Autor:
Zhihao Shen, Christy R Dillon, Shariq Siddiqui, Christopher E Bara, Dan Li, Stephen B Waldrup, Brian K. Maciver, Gulu Sandhu, Mark A. McHugh
Publikováno v:
The Journal of Supercritical Fluids. 30:273-280
Solubility data are reported for ethyl phenyl sulfide (EPS) and 2-chloroethyl ethyl sulfide (CEES) in CO 2 at temperatures from 25 to 100 °C. These two sulfide-based compounds are homomorphs for chemical warfare agents (CWAs). Both sulfide–CO 2 mi
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 152:65-76
The thermal degradation of mustard gas (ClCH2CH2SCH2CH2Cl, “HD”), with and without 5% added water, is examined. GC/MS, LC/MS and NMR were employed to comprehensively analyze the products. After 75 days at 90°C, 91% HD remains (80% with 5% water)
Autor:
George W. Wagner, Brian K. MacIver
Publikováno v:
Langmuir. 14:6930-6934
The environmental fate of chemical warfare agents is a current concern, and the notorious persistency of mustard in soil is well-known. The current study utilizes 13C MAS NMR as an in situ method to study the behavior of mustard, and the common simul
Publikováno v:
Langmuir. 11:1439-1442
Magic angle spinning (MAS) NMR can distinguish between molecules adsorbed in monolayers within the micropores (>20 A) of activated charcoal and those present in multilayers or capillary-condensed liquid in the mesopores (20-500 A). The differentiatio
Autor:
Mark A. Mchugh, Alberto Garach-Domech, Brian K. Maciver, Gulu Sandhu, David Rock, Joey Russel
Publikováno v:
Journal of Chemical & Engineering Data. 47:984-986
Pressure-composition isotherms are reported for diethyl methylphosphonate and 2-chloroethyl methyl sulfide in carbon dioxide at 35, 55, and 75 °C. These two CO 2 -polar solute systems do not exhibit three-phase equilibria in the vicinity of the crit
Publikováno v:
Archives of toxicology. 59(4)
The paucity of information regarding the characteristics of soman (pinacolyl methylphosphonofluoridate) in aqueous solution has limited its use as a toxicological or pharmacological reagent. We report here on the stability of soman under conditions i